Infrared chemiluminescence study of CO+O2 reaction on Pd(110):: Activated complex of CO2 formation at high CO coverage

被引：5
|
作者：
Nakao, K [1 ]
Ito, S [1 ]
Tomishige, K [1 ]
Kunimori, K [1 ]
机构：
[1] Univ Tsukuba, Inst Mat Sci, Tsukuba, Ibaraki 3058573, Japan
来源：
CHEMICAL PHYSICS LETTERS | 2005年 / 410卷 / 1-3期
关键词：
D O I：
10.1016/j.cplett.2005.05.052
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The infrared chemiluminescence study of CO, formed during steady-state CO + O-2 reaction over Pd(1 1 0) under various CO/O-2, pressure ratios was carried out. Highly excited antisymmetric vibrational mode compared to bending vibrational mode was observed under reaction conditions at high CO coverage. This can be related to the activated complex of CO, formation in more linear form. (c) 2005 Elsevier B.V. All rights reserved.
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页码：86 / 89
页数：4
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