N-Heterocyclic carbene catalyzed direct carbonylation of dimethylamine

被引：25
|
作者：
Li, Xiaonian [1 ]
Liu, Kun [1 ]
Xu, Xiaoliang [1 ]
Ma, Lei [1 ]
Wang, Hong [1 ]
Jiang, Dahao [1 ]
Zhang, Qunfeng [1 ]
Lu, Chunshan [1 ]
机构：
[1] Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Inst Ind Catalysis, Hangzhou 310014, Zhejiang, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 27期
基金：
中国国家自然科学基金;
关键词：
CARBON-DIOXIDE; HOMOGENEOUS HYDROGENATION; NUCLEOPHILIC CARBENES; 1,3-DI-1-ADAMANTYLIMIDAZOL-2-YLIDENE; N; N'-DIAMIDOCARBENE;
D O I：
10.1039/c1cc12047f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
N-Heterocyclic carbene (NHC) catalyzed direct carbonylation of dimethylamine leading to the formation of DMF was successfully accomplished under metal-free conditions. The catalytic efficiency was investigated and the turnover numbers can reach as high as >300. The possible mechanism was also proposed.
引用
收藏
页码：7860 / 7862
页数：3
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