Ruthenium(II) Tetradentate Schiff Base Complexes: Synthesis, Characterization, DNA Binding, and Antioxidant Studies

被引：4

作者：

Sampath, Krishnan ^{[1
]}

Jayabalakrishnan, Chinnasamy ^{[2
]}

机构：

[1] Kumaraguru Coll Technol, Dept Chem, Coimbatore, Tamil Nadu, India

[2] Sri Ramakrishna Miss Vidyalaya Coll Arts & Sci, Post Grad & Res Dept Chem, Coimbatore 641020, Tamil Nadu, India

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2015年 / 45卷 / 08期

关键词：

ruthenium(II) complexes; tetradentate Schiff base; DNA binding; antioxidant; CATALYTIC-PROPERTIES; CARBONYL-COMPLEXES; CRYSTAL-STRUCTURE; ANTIFUNGAL; LIGANDS;

D O I：

10.1080/15533174.2013.862688

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four ruthenium(II) complexes of the type [Ru(CO)(EPh3)L] (where E= P/As; L= dibasic tetradentate Schiff base ligand) have been synthesized. Structural features were determined by various physicochemical and spectral techniques. The interactions of these compounds with CT-DNA were carried out by absorption spectroscopy, which indicated that the ligands and ruthenium(II) complexes bind to DNA via intercalation. Investigation of antioxidative property showed that all the ruthenium(II) complexes have significant radical scavenging potencies against DPPH radicals than ligands.

引用

页码：1145 / 1153

页数：9

共 50 条

[1] Synthesis, DNA binding, antioxidant and cytotoxic activities of ruthenium(II) complexes of a Schiff base ligand
Subbaiyan Sathiyaraj
Krishnan Sampath
Ray J. Butcher
Chinnasamy Jayabalakrishnan
[J]. Transition Metal Chemistry, 2013, 38 : 291 - 298
[2] Synthesis, DNA binding, antioxidant and cytotoxic activities of ruthenium(II) complexes of a Schiff base ligand
Sathiyaraj, Subbaiyan
Sampath, Krishnan
Butcher, Ray J.
Jayabalakrishnan, Chinnasamy
[J]. TRANSITION METAL CHEMISTRY, 2013, 38 (03) : 291 - 298
[3] Studies on synthesis, characterization, DNA interaction and cytotoxicity of ruthenium(II) Schiff base complexes
Raja, Gunasekaran
Butcher, Ray. J.
Jayabalakrishnan, Chinnasamy
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2012, 94 : 210 - 215
[4] Synthesis, characterization and catalytic studies of ruthenium(II) Schiff base complexes
Sivasamy Kanchanadevi
Kugalur P. Balasubramanian
Vaiyapuri Chinnusamy
Ramasamy Karvembu
Karuppannan Natarajan
[J]. Transition Metal Chemistry, 2005, 30 : 330 - 333
[5] Synthesis, characterization and catalytic studies of ruthenium(II) Schiff base complexes
Kanchanadevi, S
Balasubramanian, KP
Chinnusamy, V
Karvembu, R
Natarajan, K
[J]. TRANSITION METAL CHEMISTRY, 2005, 30 (03) : 330 - 333
[6] Tetradentate Schiff base ruthenium(II) carbonyl complexes: Synthesis, characterisation, catalytic and antibacterial studies
Thangadurai, TD
Ihm, SK
[J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2003, 9 (05) : 569 - 575
[7] Novel metal complexes of flavone Schiff base: Synthesis, characterization, antioxidant and DNA binding studies
Vincent, Sharow Geeth
Jyothi, R. R. Krishna
Joseph, J.
[J]. MATERIALS TODAY-PROCEEDINGS, 2021, 45 : 1031 - 1038
[8] Synthesis, characterization, DNA binding and cleavage properties and anticancer studies of ruthenium(III) Schiff base complexes
Raja, Gunasekaran
Butcher, Ray J.
Jayabalakrishnan, Chinnasamy
[J]. TRANSITION METAL CHEMISTRY, 2012, 37 (02) : 169 - 174
[9] Synthesis, characterization, DNA binding and cleavage properties and anticancer studies of ruthenium(III) Schiff base complexes
Gunasekaran Raja
Ray J. Butcher
Chinnasamy Jayabalakrishnan
[J]. Transition Metal Chemistry, 2012, 37 : 169 - 174
[10] Synthesis, characterization and biocidal studies of ruthenium(II) carbonyl complexes containing tetradentate Schiff bases
Periasamy Viswanathamurthi
Karuppannan Natarajan
[J]. Transition Metal Chemistry, 1999, 24 : 638 - 641

← 1 2 3 4 5 →