Thermal stability and adiabatic kinetics of four explosives

被引：0
|
作者：
Feng, CG [1 ]
Liu, L [1 ]
Qian, XM [1 ]
Zhu, HQ [1 ]
机构：
[1] Beijing Inst Technol, State Key Lab Prevent & Control Explos Disasters, Beijing 100081, Peoples R China
来源：
THEORY AND PRACTICE OF ENERGETIC MATERIALS, VOL 5, PARTS A AND B | 2003年
关键词：
explosive; thermal decomposition; kinetics; ARC;
D O I：
暂无
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Four kinds of explosives, RDX, FMX, TATB and epsilon-CL-20, are studied by using Accelerating Rate Calorimeter (ARC). Their exothermic behaviors are described. The mechanisms of the thermal decomposition are discussed briefly and their kinetic parameters are determined in the present paper. The values of the activation energies of RDX, HMX, TATB and epsilon-CL-20 are 267.40, 368.66, 387.76 and 592.96 kJ(.)mol(-1) respectively, and their equations of compensation effect are respectively ln A = 0.2741E - 7.7087, ln A = 0.2414E - 7.1786, ln A = 0.2063E - 9.7128 and ln A = 0.2497E - 6.7068.
引用
收藏
页码：177 / 182
页数：6
相关论文
共 50 条
  • [1] Investigation on thermal stability of five industrial explosives by adiabatic technique
    Fu, ZM
    Huang, JY
    Ma, L
    Qian, XM
    Jiang, HL
    [J]. THEORY AND PRACTICE OF ENERGETIC MATERIALS, VOL 5, PARTS A AND B, 2003, : 251 - 255
  • [2] Thermal stability of explosives
    Folly, P
    [J]. CHIMIA, 2004, 58 (06) : 394 - 400
  • [3] Determination of the Thermal Stability of Explosives
    Nazin, G. M.
    Korsunskiy, B. L.
    [J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B, 2021, 15 (02) : 271 - 277
  • [4] Determination of the Thermal Stability of Explosives
    G. M. Nazin
    B. L. Korsunskiy
    [J]. Russian Journal of Physical Chemistry B, 2021, 15 : 271 - 277
  • [5] Research and application of thermal decomposition kinetics for explosives
    Gao, Da-Yuan
    Dong, Hai-Shan
    Li, Bo-Tao
    He, Bi
    [J]. Hanneng Cailiao/Energetic Materials, 2004, 12 (SUPPL.):
  • [6] Statistical analysis of kinetics of an adiabatic thermal explosion
    Medvedev, V. G.
    Telegin, V. G.
    Telegin, G. G.
    [J]. COMBUSTION EXPLOSION AND SHOCK WAVES, 2009, 45 (03) : 274 - 277
  • [7] Statistical analysis of kinetics of an adiabatic thermal explosion
    V. G. Medvedev
    V. G. Telegin
    G. G. Telegin
    [J]. Combustion, Explosion, and Shock Waves, 2009, 45 : 274 - 277
  • [8] KINETICS AND MECHANISMS OF THERMAL-DECOMPOSITION OF NITROAROMATIC EXPLOSIVES
    BRILL, TB
    JAMES, KJ
    [J]. CHEMICAL REVIEWS, 1993, 93 (08) : 2667 - 2692
  • [9] THERMAL-STABILITY OF DIMETHYLSULFOXIDE IN ADIABATIC CONDITIONS
    CARDILLO, P
    GIRELLI, A
    [J]. CHIMICA & L INDUSTRIA, 1982, 64 (04): : 231 - 234
  • [10] The kinetic behaviour and thermal stability of commercially available explosives
    Krabbendam-LaHaye, ELM
    de Klerk, WPC
    Krämer, RE
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2005, 80 (02) : 495 - 501
12345