Autothermal CO2 reforming of methane over NiO-MgO solid solution catalysts under pressurized condition -: Effect of fluidized bed reactor and its promoting mechanism

被引:67
|
作者
Matsuo, Y [1 ]
Yoshinaga, Y [1 ]
Sekine, Y [1 ]
Tomishige, K [1 ]
Fujimoto, K [1 ]
机构
[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan
基金
日本学术振兴会;
关键词
autothermal reforming; NiO-MgO solid solution; fluidized bed reactor;
D O I
10.1016/S0920-5861(00)00489-2
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The effect of fluidized bed reactor in autothermal CO2 reforming of methane over NiO-MgO solid solution catalysts was investigated by comparing with fixed bed reactor. Methane conversion to syngas was drastically enhanced by using a fluidized bed reactor. The catalyst was reduced and oxidized repeatedly in fluidized bed reactor during the reaction. The enhancement of methane conversion is related to the catalyst reducibility. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:439 / 445
页数:7
相关论文
共 44 条
  • [21] Role of lattice oxygen during CO2 reforming of methane over NiO/MgO solid solutions
    Eli Ruckenstein
    Yun Hang Hu
    [J]. Catalysis Letters, 1998, 51 : 183 - 185
  • [22] Role of lattice oxygen during CO2 reforming of methane over NiO/MgO solid solutions
    Ruckenstein, E
    Hu, YH
    [J]. CATALYSIS LETTERS, 1998, 51 (3-4) : 183 - 185
  • [23] Autothermal Reforming of Methane with Integrated CO2 Capture in a Novel Fluidized Bed Membrane Reactor. Part 1: Experimental Demonstration
    F. Gallucci
    M. Van Sint Annaland
    J. A. M. Kuipers
    [J]. Topics in Catalysis, 2008, 51 : 133 - 145
  • [24] Autothermal Reforming of Methane with Integrated CO2 Capture in a Novel Fluidized Bed Membrane Reactor. Part 1: Experimental Demonstration
    Gallucci, F.
    Annaland, M. Van Sint
    Kuipers, J. A. M.
    [J]. TOPICS IN CATALYSIS, 2008, 51 (1-4) : 133 - 145
  • [25] Critical role of isolation effect in solid solution catalysts for CO2 reforming of methane
    Hu, Yun
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [26] The effect of precursor and preparation conditions of MgO on the CO2 reforming of CH4 over NiO/MgO catalysts
    Ruckenstein, E
    Hu, YH
    [J]. APPLIED CATALYSIS A-GENERAL, 1997, 154 (1-2) : 185 - 205
  • [28] Insight into the reaction mechanism of CO2 activation for CH4 reforming over NiO-MgO: A combination of DRIFTS and DFT study
    Jiang, Shiping
    Lu, Yao
    Wang, Shengping
    Zhao, Yujun
    Ma, Xinbin
    [J]. APPLIED SURFACE SCIENCE, 2017, 416 : 59 - 68
  • [29] CO2 reforming of CH4 over Co/MgO solid solution catalysts -: effect of calcination temperature and Co loading
    Wang, HY
    Ruckenstein, E
    [J]. APPLIED CATALYSIS A-GENERAL, 2001, 209 (1-2) : 207 - 215
  • [30] Syngas production from reforming of methane with CO2 and O2 over Ni/SrO-SiO2 catalysts in a fluidized bed reactor
    Jing, QS
    Lou, H
    Fei, JH
    Hou, ZY
    Zheng, XM
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2004, 29 (12) : 1245 - 1251