[(C3H4N2)2Au]Cl-a bis protic gold(I)-NHC

被引：48

作者：

Kunz, Peter C. ^{[1
]}

Wetzel, Corinna ^{[1
]}

Koegel, Susanne ^{[2
]}

Kassack, Matthias U. ^{[2
]}

Spingler, Bernhard ^{[3
]}

机构：

[1] Univ Dusseldorf, Inst Anorgan Chem & Strukturchem, D-40225 Dusseldorf, Germany

[2] Univ Dusseldorf, Inst Pharmazeut & Med Chem, D-40225 Dusseldorf, Germany

[3] Univ Zurich Irchel, Inst Anorgan Chem, CH-8057 Zurich, Switzerland

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 01期

关键词：

N-HETEROCYCLIC CARBENE; TRANSITION-METAL-COMPLEXES; COMPUTATIONAL ASSESSMENT; LIGANDS; GOLD; AU; AG;

D O I：

10.1039/c0dt01089h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The gold(I) bis-NHC (NHC = imidazol-2-ylidene) parent compound was synthesised in high yield by a three step reaction starting from imidazole. The compound is highly water soluble and stable in concentrated hydrochloric acid.

引用

页码：35 / 37

页数：3

共 50 条

[11] CRYSTAL AND MOLECULAR STRUCTURE OF TETRAKISPYRAZOLE-NICKEL CHLORIDE NI(C3H4N2)4CL2
REIMANN, CW
MIGHELL, AD
MAUER, FA
[J]. ACTA CRYSTALLOGRAPHICA, 1967, 23 : 135 - &
[12] ORGANOURANIUM COMPLEXES OF PYRAZOLE AND PYRAZOLATE - SYNTHESIS AND X-RAY STRUCTURES OF U(C5ME5)2CL2(C3H4N2), U(C5ME5)2CL(C3H4N2), AND U(C5ME5)(C3H3N2)2
EIGENBROT, CW
RAYMOND, KN
[J]. INORGANIC CHEMISTRY, 1982, 21 (07) : 2653 - 2660
[13] TRANS-DIAQUATETRAKIS(IMIDAZOLE)MANGANESE(II) DICHLORIDE, [MN(C3H4N2)4(H2O)2]CL2
GARRETT, TPJ
GUSS, JM
FREEMAN, HC
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1983, 39 (AUG) : 1031 - 1034
[14] MOLECULAR AND CRYSTAL STRUCTURE OF DIIMIDAZOLE SILVER(I) NITRATE, AG(C3H4N2)2NO3
ANTTI, CJ
LUNDBERG, BK
[J]. ACTA CHEMICA SCANDINAVICA, 1971, 25 (05): : 1758 - &
[15] SYNTHESIS AND CRYSTAL-STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)GOLD TRICYANOMETHANIDE, [(PPH3)2AU]+ [C(CN)3]-
BAUKOVA, TV
KRAVTSOV, DN
KUZMINA, LG
DVORTSOVA, NV
PORAYKOSHITS, MA
PEREVALOVA, EG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 372 (03) : 465 - 471
[16] STRUCTURES OF 2 GOLD(I) COMPLEXES WITH TRICYCLOHEXYLPHOSPHINE - [(CY3P)AUCL] AND [(CY3P)2AU]+.CL-
MUIR, JA
MUIR, MM
PULGAR, LB
JONES, PG
SHELDRICK, GM
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (AUG) : 1174 - 1176
[17] Magnetism of Co(C3H4N2)2(CO3)(H2O)2
Swiatek-Tran, B
Kolodziej, HA
Tran, VH
Baenitz, M
Vogt, A
[J]. PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 2003, 196 (01): : 232 - 235
[18] trans-bis(cyanamidonitrato-N:O)bis(imidazole-N3)copper(II), [Cu(CN3O2)2(C3H4N2)2]
Slovak Technical Univ, Bratislava, Slovakia
[J]. Acta Crystallogr Sect C Cryst Struct Commun, pt 6 (703-705):
[19] MIXED-VALENT LINEAR-CHAINS OF GOLD ATOMS - X-RAY STRUCTURE OF [((2,4,6-C6F3H2)AU(CH2PPH2CH2)2AU)2AU(CH2PPH2CH2)2AU](CLO4)2
LAGUNA, A
LAGUNA, M
JIMENEZ, J
LAHOZ, FJ
OLMOS, E
[J]. ORGANOMETALLICS, 1994, 13 (01) : 253 - 257
[20] STRUCTURE OF TRANS-BIS(DIMETHYLPHENYLPHOSPHINE)BIS(PYRAZOLE)PLATINUM, [PT(C3H4N2)2-(P(CH3)2(C6H5))2]
OLIVER, JD
MULLICA, DF
GROSSIE, DA
MILLIGAN, WO
PERKINS, HO
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (MAY) : 746 - 748

← 1 2 3 4 5 →