A new nasicon-type phosphate:: Co0.5Ti2(PO4)3 II.: Simulation of optical and magnetic properties

被引：7
|
作者：
Derouet, J
Beaury, L
Porcher, P
Olazcuaga, R
Dance, JM
Le Flem, G
El Bouari, A
El Jazouli, A
机构：
[1] ENSCP, Lab Chim Appl Etat Solide, F-75231 Paris 05, France
[2] Inst Chim Mat Condensee, CNRS UPR9048, F-33608 Pessac, France
[3] Fac Sci MSik Sidi Othmane, Dept Chim, Casablanca, Morocco
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 1999年 / 143卷 / 02期
关键词：
D O I：
10.1006/jssc.1998.8098
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The optical (energy level scheme) and magnetic properties (paramagnetic susceptibility as a function of the temperature and g values) of the polycrystalline Co0.5Ti2(PO4)(3) mere simultaneously reproduced by use of a crystal field theory involving a set of F-k, zeta, free ion, and B-q(k) crystal field parameters. The crystal field parameters calculated from the structure are in fair agreement with the experimental ones and permit us to assign R32 as the space group of the crystal structure. (C) 1999 Academic Press.
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页码：230 / 238
页数：9
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