Synthesis and structure of carboxylate-bridged polynuclear copper(II)-lanthanum(III) ring:: [La(H2O)5(CuL)2][CuL] • 8H2O

被引：3
|
作者：
Zou, Y [1 ]
Liu, WL
Ni, CL
Ni, ZP
Yao, YG
Meng, QJ
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Dept Chem, Nanjing 210093, Peoples R China
[2] Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 01期
基金：
中国国家自然科学基金;
关键词：
Cu(II)-La(III) complex; hexa-nuclear cation; crystal structure; dipeptide;
D O I：
10.1016/j.inoche.2003.10.015
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of the Na[CuL] (where L = Schiff base derived from 5-bromosalicylaldehyde and glycylglycine) with LaCl3.nH(2)O leads to the formation of the title complex 1 [La(H2O)(5)(CuL)(2)][CuL].8H(2)O which containing ring-like hexa-nuclear [La-2(H2O)(10) (CuL)(4)](2+) cation. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：101 / 103
页数：3
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