Lithium salicylate monohydrate:: A layer structure with carboxylate-bridged Δ- and Λ-[(H2O)Li+]∞ helices

被引：17
|
作者：
Wiesbrock, F [1 ]
Schmidbaur, H [1 ]
机构：
[1] Univ Munich, Anorgan Chem Inst, D-85747 Garching, Germany
来源：
CRYSTENGCOMM | 2003年 / 5卷
关键词：
D O I：
10.1039/b312892j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Lithium salicylate crystallizes from aqueous solutions as the monohydrate ( space group P2(1)/c). In its layer structure, alternating Delta- and Lambda-[(H2O)Li+](infinity) helices run parallel along the b-axis. These helices are double-bridged at the tetracoordinate lithium cations by the carboxylate groups of the salicylate anions.
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收藏
页码：503 / 505
页数：3
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