Attempt to resolute chiral clusters by optically active hydrazide

被引:0
|
作者
Zhang, YH [1 ]
Zhang, WQ [1 ]
Chen, YG [1 ]
Chen, Z [1 ]
Zhu, XY [1 ]
Jing, HW [1 ]
Yin, YQ [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
关键词
chiral clusters; optically active hydrazone; chiral resolution; diastereoisomer; HMBC;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new kind of hydrazone (I) diastereoisomers was prepared with enantiomeric hydazide (II) and chiral cluster (III), which was characterized by HMBC. Unfortunately, the mixture could not be separated into pure diastereoisomer. This could be a direction to separate the racemic chiral clusters.
引用
收藏
页码:69 / 70
页数:2
相关论文
共 50 条
  • [41] Preparation of Chiral Epoxy Resins and the Optically Active Cured Products
    Tang, Xinyuan
    Hu, Ming
    Liu, Xiaoran
    Li, Yanyun
    Zhang, Junying
    Cheng, Jue
    ADVANCES IN POLYMER TECHNOLOGY, 2023, 2023
  • [42] Synthesis and chiroptical analysis of optically active chiral shell dendrons
    Junge, DM
    Wu, MJ
    McElhanon, JR
    McGrath, DV
    JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (17): : 5306 - 5314
  • [43] Convenient transformation of optically active nitroalkanes into chiral aldoximes and nitriles
    Czekelius, C
    Carreira, EM
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (04) : 612 - 615
  • [44] Spontaneous emission of an optically active molecule near a chiral nanoellipsoid
    Guzatov, Dmitry, V
    Klimov, Vasily V.
    PHYSICAL REVIEW A, 2018, 98 (01)
  • [45] Optically active dendrimers based on the planar chiral ferrocene core
    N. S. Khrushcheva
    V. I. Sokolov
    Russian Chemical Bulletin, 2008, 57 : 1244 - 1246
  • [46] OPTICALLY-ACTIVE STARTING MATERIALS FOR THE SYNTHESIS OF CHIRAL DRUGS
    BRUSSEE, J
    JANSEN, ACA
    KUHN, A
    PHARMACEUTISCH WEEKBLAD-SCIENTIFIC EDITION, 1984, 6 (06) : 258 - 258
  • [47] CHIRAL REFLECTION FROM A NATURALLY OPTICALLY-ACTIVE MEDIUM
    SILVERMAN, MP
    BADOZ, J
    BRIAT, B
    OPTICS LETTERS, 1992, 17 (12) : 886 - 888
  • [48] Synthesis of optically active dendrimers having chiral bisphosphine as a core
    Ouchi, Yuko
    Morisaki, Yasuhiro
    Chujo, Yoshiki
    POLYMER BULLETIN, 2007, 59 (03) : 339 - 349
  • [50] Noncovalent Chiral Functionalization of Graphene with Optically Active Helical Polymers
    Ren, Chonglei
    Chen, Yu
    Zhang, Haiyang
    Deng, Jianping
    MACROMOLECULAR RAPID COMMUNICATIONS, 2013, 34 (17) : 1368 - 1374