New glyoxime derivatives and their transition metal complexes

被引:7
|
作者
Yildirim, B. [1 ]
Oezcan, E. [1 ]
Deveci, P. [1 ]
机构
[1] Selcuk Univ, Fac Arts & Sci, Dept Chem, Konya, Turkey
关键词
D O I
10.1134/S1070328407060061
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two new vic-dioxime ligands and their complexes with Co+2, Ni+2, Cu+2, Cd+2, and Zn+2 ions were synthesized. Primer amines (3,4-methylenedioxaaniline and 4-methylbenzylamine) reacted with antichloroglyoxime to give 3,4-methylenedioxaphenylaminoglyoxime (H2L1) and N-(4-methylbenzyl)aminoglyoxime (H2L2) ligands. Structures of the ligands and their complexes are proposed based on elemental analyses, IR, UV-Vis, and H-1 NMR spectra, magnetic susceptibility measurements, and thermogravi metric analyses (TGA).
引用
收藏
页码:417 / 421
页数:5
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