A phenanthroimidazole-based fluorescent probe for ratiometric detection of CIO

被引:10
|
作者
Yang, Xiaofeng [1 ]
Zheng, Yan [2 ]
Zheng, Luyi [1 ]
机构
[1] Univ Jinan, Sch Chem & Chem Engn, 336 West Rd Nan Xinzhuang, Jinan 250022, Shandong, Peoples R China
[2] Shandong First Med Univ, Shandong Prov Hosp, 324 Jingwuweiqi Rd, Jinan 250021, Shandong, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
ClO-Ratiometric; Fluorescent probe; Selective; HYPOCHLOROUS-ACID; HOCL; MYELOPEROXIDASE; OXIDATION; OXIDANT; SIGNAL; BOND; CELL;
D O I
10.1016/j.jphotochem.2021.113575
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hypochlorite anion (ClO- ), on the one hand, is widely used in household bleaching, drinking water disinfection and other daily life; on the other hand, as one of the biologically important reactive oxygen species, plays an important role in immune system and some human diseases. Herein, a phenanthroimidazole-based fluorescent probe, 1, has been successfully developed for the detection of ClO- . Compound 1 displayed a fluorescence color change from blue to aquamarine and a remarkable ratiometric fluorescence response towards ClO- with rapid response (completed within 5 s) and high sensitivity (detection limit is 26.8 nM.). Additionally, compound 1 would be a potential tool to detection NaClO concentration in several tap water and 84 disinfectant samples.
引用
收藏
页数:7
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