Shaping Covalent Triazine Frameworks for the Hydrogenation of Carbon Dioxide to Formic Acid

被引：72

作者：

Bavykina, Anastasiya V. ^{[1
]}

Rozhko, Elena ^{[1
]}

Goesten, Maarten G. ^{[1
,2
]}

Wezendonk, Tim ^{[1
]}

Seoane, Beatriz ^{[1
]}

Kapteijn, Freek ^{[1
]}

Makkee, Michiel ^{[1
]}

Gascon, Jorge ^{[1
]}

机构：

[1] Delft Univ Technol, Catalysis Engn ChemE, Julianalaan 136, NL-2628 BL Delft, Netherlands

[2] Eindhoven Univ Technol, Dept Chem Engn & Chem Mol Catalysis, Kranenveld 14, NL-5600 MB Eindhoven, Netherlands

来源：

CHEMCATCHEM | 2016年 / 8卷 / 13期

关键词：

carbon dioxide hydrogenation; catalyst shaping; covalent triazine frameworks; formic acid; CATALYTIC-HYDROGENATION; CO2; OXIDATION;

D O I：

10.1002/cctc.201600419

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A facile one-step method to shape covalent triazine frameworks (CTFs) for catalytic applications is reported. Phase inversion of the CTF powder by using a polyimide as a binder in a microfluidic device results in the formation of composite spheres with accessible CTF porosity and a high mechanical and thermal stability. The fabricated spheres can be used to host organometallic complexes. The obtained shaped catalysts, Ir@CTF spheres, are active and fully recyclable in the direct hydrogenation of carbon dioxide into formic acid under mild reaction conditions (20 bar and 50-90 degrees C) and in the dehydrogenation of formic acid.

引用

页码：2217 / 2221

页数：5

共 50 条

[41] Reversible Hydrogenation of Carbon Dioxide to Formic Acid and Methanol: Lewis Acid Enhancement of Base Metal Catalysts
Bernskoetter, Wesley H.
Hazari, Nilay
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 2017, 50 (04) : 1049 - 1058
[42] Utilization of Carbon Dioxide as a Hydrogen Storage Material: Hydrogenation of Carbon Dioxide and Decomposition of Formic Acid Using Iridium Complex Catalysts
Himeda, Yuichiro
[J]. ADVANCES IN CO2 CONVERSION AND UTILIZATION, 2010, 1056 : 141 - 153
[43] ACTIVATION OF CARBON-DIOXIDE .4. RHODIUM-CATALYZES HYDROGENATION OF CARBON-DIOXIDE TO FORMIC-ACID
LEITNER, W
DINJUS, E
GASSNER, F
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 475 (1-2) : 257 - 266
[44] Enhanced activity for the catalytic hydrogenation of carbon dioxide to formic acid with sub-stoichiometric additives
Drake, Jessica L.
Manna, Cesar M.
Vasilopoulos, Aristidis
Byers, Jeffery A.
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
[45] Carbon Dioxide Hydrogenation to Formic Acid with Self-Separating Product and Recyclable Catalyst Phase
Ehmann, Kira R.
Nisters, Arne
Vorholt, Andreas J.
Leitner, Walter
[J]. CHEMCATCHEM, 2022, 14 (19)
[46] Catalyst design for highly efficient carbon dioxide hydrogenation to formic acid under buffering conditions
Weilhard, Andreas
Salzmann, Kevin
Navarro, Miquel
Dupont, Jairton
Albrecht, Martin
Sans, Victor
[J]. JOURNAL OF CATALYSIS, 2020, 385 : 1 - 9
[47] Reversible hydrogenation/dehydrogenation of carbon dioxide/formic acid and aqueous alkali metal bicarbonates/formates
Joo, Ferenc
Kovacs, Henrietta
Katho, Agnes
Papp, Gabor
Horvath, Henrietta
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
[48] Cu dispersed TiO2 catalyst for direct hydrogenation of carbon dioxide into formic acid
Pandey, Preeti H.
Pawar, Hitesh S.
[J]. JOURNAL OF CO2 UTILIZATION, 2020, 41
[49] Towards a continuous formic acid synthesis: a two-step carbon dioxide hydrogenation in flow
Reymond, Helena
Jose Corral-Perez, Juan
Urakawa, Atsushi
von Rohr, Philipp Rudolf
[J]. REACTION CHEMISTRY & ENGINEERING, 2018, 3 (06): : 912 - 919
[50] Covalent triazine frameworks - a sustainable perspective
Krishnaraj, Chidharth
Jena, Himanshu Sekhar
Leus, Karen
Van der Voort, Pascal
[J]. GREEN CHEMISTRY, 2020, 22 (04) : 1038 - 1071

← 1 2 3 4 5 →