Dew points of quaternary ethane plus carbon dioxide plus water plus methanol mixtures -: Measurement and modelling

被引：3
|
作者：
Jarne, C [1 ]
Blanco, ST
Avila, S
Berro, C
Otín, S
Velasco, I
机构：
[1] Univ Zaragoza, Fac Ciencias, Dept Quim Organ & Quim Fis, E-50009 Zaragoza, Spain
[2] Univ Mediterranee, Fac Sci Luminy, Lab Chim Phys Marseille, F-13288 Marseille, France
来源：
CANADIAN JOURNAL OF CHEMISTRY | 2005年 / 83卷 / 03期
关键词：
dew point; equation of state; excess function;
D O I：
10.1139/V05-040
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dew points have been measured for eight ethane + carbon dioxide + water + methanol mixtures at pressures from 0.11 to 2.17 MPa and temperatures from 249.0 to 288.7 K. The results are analysed in terms of a predictive excess-function equation of state ( EF-EOS) method based on the zeroth approximation of Guggenheim's reticular model. This method can be used to adequately predict the dew points of the mixtures in the temperature and pressure ranges used in the present study. In fact, the model reproduces the experimental dew point temperature data with <= 3.1 K average absolute deviation.
引用
收藏
页码：220 / 226
页数：7
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