Soluble polypyrrole copolymers

被引:32
|
作者
Ustamehmetoglu, B [1 ]
Kizilcan, N [1 ]
Saraç, AS [1 ]
Akar, A [1 ]
机构
[1] Tech Univ Istanbul, Fac Sci, Dept Chem, TR-80620 Maslak, Istanbul, Turkey
关键词
soluble polypyrroles; chemical polymerization; ketonic resin-pyrrole co-polymers; ethyl methyl ketone-formaldehyde resin; conductive polymers;
D O I
10.1002/app.1944
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Anew class of dimethyl formamide (DMF)- and acetone-soluble conducting pyrrole-ketonic resin copolymers has been developed. This was accomplished by oxidatively polymerizing pyrrole monomer by Ce(IV) salt in the presence of methyl ethyl ketone formaldehyde resin (MEKF-R). The resulting copolymers were readily dissolved in DMF and acetone. These products were characterized by FTIR and UV-visible spectroscopy, conductivity, four-probe conductivity, viscosity, and DSC measurements. (C) 2001 John Wiley & Sons, Inc.
引用
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页码:1098 / 1106
页数:9
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