Analysis of toxic products of thermal decomposition and combustion of substrates used in the synthesis of polyurethanes

被引：1

作者：

Sankowska, Monika ^{[1
]}

Gajek, Agnieszka ^{[2
]}

Celinski, Maciej ^{[3
]}

机构：

[1] Panstwowy Inst Badawczy, Cent Inst Ochrony Pracy, Warsaw, Poland

[2] Panstwowy Inst Badawczy, Cent Inst Ochrony Pracy, Zakladzie Zagrozen Chem & Pylowych, Pracowni Bezpieczenstwa Chem, Warsaw, Poland

[3] Panstwowy Inst Badawczy, Cent Inst Ochrony Pracy, Zakladzie Zagrozen Chem Pylowych & Biol, Warsaw, Poland

来源：

PRZEMYSL CHEMICZNY | 2016年 / 95卷 / 06期

关键词：

DEGRADATION; FOAMS; STABILITY;

D O I：

10.15199/62.2016.6.32

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ignition time, rate of heat secretion and total amt. of smoke were detd. by using a cone calorimeter for an cyanate, a polyol and a surfactant used for com. prodn. of polyurethanes. The ignition times were 23, 36 and 32 s, resp., and rates of heat secretion 247.7, 675.2 and 498.8 kW/m(2), resp. The combustion of polyol released approx. 20 times less of smoke than combustion of other substrates. The chem. compn. of flue gases was detd. by IR spectrofotometty with Fourier transformation and gas chromatog. coupled with mass spectrometry. C oxides and H2O were main prods. of combustion. Some hydrocarbons were also present in trace amts.

引用

页码：1237 / 1242

页数：6

共 50 条

[31] Combustion Synthesis and Catalytic Activity of LaCoO3 for HMX Thermal Decomposition
Wei, Zhi-Xian
Chi, Ying-Nan
Hu, Chang-Wen
Liu, Hai-Yan
[J]. PROPELLANTS EXPLOSIVES PYROTECHNICS, 2009, 34 (05) : 394 - 399
[32] Oil in porous substrates: a thermogravimetric and simultaneous thermal analysis of spontaneous combustion risk
Ouyang, Shin-Mei
Chen, Yu-Jen
Chen, Chin-Feng
Chen, Wei-Chun
[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2023, 148 (11) : 4669 - 4679
[33] Oil in porous substrates: a thermogravimetric and simultaneous thermal analysis of spontaneous combustion risk
Shin-Mei Ouyang
Yu-Jen Chen
Chin-Feng Chen
Wei-Chun Chen
[J]. Journal of Thermal Analysis and Calorimetry, 2023, 148 : 4669 - 4679
[34] Behavior of toxic elements in the thermal decomposition of industrial sodium jarosite: a kinetic analysis
Olcay, Ruben H.
Palacios, Elia G.
Reyes, Ivan A.
Patino, Francisco
Reyes, Martin
Perez, Miguel
Islas, Hernan
Juarez, Julio C.
Flores, Mizraim U.
[J]. REACTION KINETICS MECHANISMS AND CATALYSIS, 2024,
[35] Principal component analysis of thermal decomposition of magnesium salts used as drugs
Szynkaruk, Piotr
Wesolowski, Marek
Samson-Rosa, Malgorzata
[J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2010, 101 (02) : 505 - 512
[36] Principal component analysis of thermal decomposition of magnesium salts used as drugs
Piotr Szynkaruk
Marek Wesolowski
Malgorzata Samson-Rosa
[J]. Journal of Thermal Analysis and Calorimetry, 2010, 101 : 505 - 512
[37] Effect of potassium salt flame suppressors on the thermal decomposition behavior of the combustion catalysts used in solid propellant
Zhao, Feng-Qi
Chen, Pei
Li, Shang-Wen
Yin, Cui-Mei
Liu, Zi-Ru
[J]. Guti Huojian Jishu/Journal of Solid Rocket Technology, 2002, 25 (01):
[38] Thermal Decomposition Behavior during Combustion of Hydrothermally Treated MSW by Thermogravimetric Analysis
Phasee, Phatavee
Areeprasert, Chinnathan
[J]. 2017 INTERNATIONAL CONFERENCE ON ALTERNATIVE ENERGY IN DEVELOPING COUNTRIES AND EMERGING ECONOMIES, 2017, 138 : 616 - 621
[39] Combustion synthesis of LiMn2O4 by thermal decomposition of oxalate precursors
Lagashetty, Arunkumar
Havanoor, Vijayanand
Basavaraja, S.
Venkataraman, A.
[J]. INDIAN JOURNAL OF CHEMICAL TECHNOLOGY, 2008, 15 (01) : 41 - 44
[40] ANALYSIS OF PRODUCTS OF THERMAL-DECOMPOSITION OF A CHLORINATED AROMATIC POLYAMIDE FABRIC
CHATFIELD, DA
EINHORN, IN
MICKELSON, RW
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1976, 172 (SEP3): : 91 - 91

← 1 2 3 4 5 →