Applications of α-Phosphonovinyl Tosylates in the Synthesis of α-Arylethenylphosphonates via Suzuki-Miyaura Cross-Coupling Reactions

被引：25
|
作者：
Fang, Yewen [1 ]
Zhang, Li [2 ]
Li, Jinjian [1 ]
Jin, Xiaoping [3 ]
Yuan, Meijuan [2 ]
Li, Ruifeng [2 ]
Wu, Rong [1 ]
Fang, Jianghua [1 ]
机构：
[1] Ningbo Univ Technol, Sch Chem Engn, Ningbo 315016, Zhejiang, Peoples R China
[2] Taiyuan Univ Technol, Coll Chem & Chem Engn, Taiyuan 030024, Peoples R China
[3] Zhejiang Pharmaceut Coll, Dept Biol & Pharmaceut Sci, Ningbo 315100, Zhejiang, Peoples R China
来源：
ORGANIC LETTERS | 2015年 / 17卷 / 04期
基金：
中国国家自然科学基金;
关键词：
ENANTIOSELECTIVE HYDROGENATION; PALLADIUM CATALYST; ARYLBORONIC ACIDS; ARYL; PHOSPHONATES; CHLORIDES; REAGENTS; ETHERS;
D O I：
10.1021/ol503518h
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
It has been demonstrated for the first time that alpha-phosphonovinyl tosylates could efficiently couple with a range of arylboronic acids to access alpha-arylethenylphosphonates. The unprecedented procedure exhibits excellent functional group tolerance, giving the terminal vinylphosphonates in good to excellent isolated yields (60-99%) under mild reaction conditions.
引用
收藏
页码：798 / 801
页数：4
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