Synthesis and structure of (Me2PhP)3Cl2ReN-ReCl4(PMe2Ph), a mixed valent dinuclear complex with a nitrido bridge between ReV and ReIV

被引：0

作者：

Haug, A ^{[1
]}

Strahle, J ^{[1
]}

机构：

[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 06期

关键词：

mixed valent Re-IV/V nitrido complex; nitrido bridge between Re-IV and Re-V; synthesis; crystal structure; magnetic properties;

D O I：

10.1002/(SICI)1521-3749(199806)624:6<931::AID-ZAAC931>3.3.CO;2-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The nitrido complex (Me2PhP)(3)Cl2Re=N-ReCl4(PMe2Ph) results from the reaction of ReNCl2(PMe2Ph)(3) with GeCl4 in toluene. The mixed valent dinuclear complex is paramagnetic with mu(eff) = 1.96 B.M. at 300 K. It crystallizes with one solvate molecule as red crystals (Me2PhP)(3)Cl2Re=N-ReCl4(PMe2Ph). C7H8 with the space group P (1) over bar and a = 1075.4(6), b = 1330.5(6), c = 1745.3(11) pm, alpha = 101.20(3), beta = 105.88(3), gamma = 94.23(3)degrees, Z = 2. In the dinuclear complex one molecule ReNCl2(PMe2Ph)(3) coordinates with its nitrido ligand to a fragment ReCl4(PMe2Ph). The resulting nitrido bridge is asymmetrical with distances Re-N of 170.6(6) and 205.5(6) pm, and a bond angle Re1-N-Re2 = 174.6(3)degrees.

引用

页码：931 / 933

页数：3

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