3D-Network porous polymer bonded metalloporphyrin: An efficient and reusable catalyst for the Baeyer-Villiger oxidation

被引:2
|
作者
Hamid, Sheida [1 ]
Mouradzadegun, Arash [1 ]
机构
[1] Shahid Chamran Univ Ahvaz, Fac Sci, Dept Chem, Ahvaz, Iran
关键词
Network porous polymer; metalloporphyrin; Baeyer-Villiger oxidation; MOLECULAR-OXYGEN; KETONES; CYCLOHEXANONE; DEGRADATION; FACILE;
D O I
10.1142/S1088424621501273
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new, green catalyst was prepared through immobilization of metalloporphyrin on the surface of 3D-network polymer based on calix[4]resorcinarene (PC4RA), which efficiently catalyze B-V oxidation reaction using O-2/benzaldehyde. The catalyst demonstrated excellent activity, which is highly potential for cyclic aliphatic ketones oxidation under mild conditions. IR spectroscopy, UV-Vis spectroscopy, thermal gravimetric analysis, energy dispersive spectroscopy and scanning electron microscopy are some of the spectroscopic methods used to characterize the new synthesized solid support. The synthesis of a novel, green and recoverable heterogeneous catalyst was investigated by grafting Cu-porphyrin on the surface of polymeric calix[4]resorcinarene for Baeyer-Villiger oxidation. The catalyst demonstrated excellent activity, especially in the case where cyclic aliphatic ketone oxidation was easily perfomed under mild conditions with high yields.
引用
收藏
页码:171 / 179
页数:9
相关论文
共 49 条
  • [21] A metalloporphyrin-based porous organic polymer as an efficient catalyst for the catalytic oxidation of olefins and arylalkanes
    Ding, Zheng-Dong
    Zhu, Wei
    Li, Tao
    Shen, Rui
    Li, Yunxing
    Li, Zaijun
    Ren, Xuehong
    Gu, Zhi-Guo
    DALTON TRANSACTIONS, 2017, 46 (34) : 11372 - 11379
  • [22] Efficient Co3O4/SiO2 catalyst for the Baeyer–Villiger oxidation of cyclohexanone
    Juan Zang
    Yunjie Ding
    Yanpeng Pei
    Jia Liu
    Ronghe Lin
    Li Yan
    Tao Liu
    Yuan Lu
    Reaction Kinetics, Mechanisms and Catalysis, 2014, 112 : 159 - 171
  • [23] Baeyer-Villiger Oxidation of Cyclohexanone by Hydrogen Peroxide with Fe3O4@GO as Catalyst Under Solvent Free Conditions
    Xiao, Guansheng
    Gao, Xi
    Yan, Weiting
    Wu, Tao
    Peng, Xinhua
    CATALYSIS LETTERS, 2019, 149 (07) : 1765 - 1771
  • [24] Graphene oxide supported chlorostannate (IV) ionic liquid: Bronsted-Lewis acidic combined catalyst for highly efficient Baeyer-Villiger oxidation in water
    Xing, Chen
    Tan, Rong
    Hao, Pengbo
    Gao, Mengqiao
    Yin, Donghong
    Yin, Dulin
    MOLECULAR CATALYSIS, 2017, 433 : 37 - 47
  • [25] Synthesis and characterization of porous organic polymer containing tailored AB3 metalloporphyrin: highly active and reusable catalyst for oxidation of benzyl alcohol
    Mouradzadegun, Arash
    Hamid, Sheida
    Takabi, Asiyeh Sheikhzadeh
    RESEARCH ON CHEMICAL INTERMEDIATES, 2021, 47 (12) : 4943 - 4955
  • [26] Synthesis and characterization of porous organic polymer containing tailored AB3 metalloporphyrin: highly active and reusable catalyst for oxidation of benzyl alcohol
    Arash Mouradzadegun
    Sheida Hamid
    Asiyeh Sheikhzadeh Takabi
    Research on Chemical Intermediates, 2021, 47 : 4943 - 4955
  • [27] Stabilized Fe3O4 magnetic nanoparticles into nanopores of modified montmorillonite clay: a highly efficient catalyst for the Baeyer-Villiger oxidation under solvent free conditions
    Saikia, Pallab Kumar
    Sarmah, Podma Pollov
    Borah, Bibek Jyoti
    Saikia, Lakshi
    Saikia, Kokil
    Dutta, Dipak Kumar
    GREEN CHEMISTRY, 2016, 18 (09) : 2843 - 2850
  • [28] Baeyer-villiger oxidation of cyclohexanone to caprolactone over highly efficient MgO/SnO2 catalyst using H2O2 as oxidant
    Li Jing-Xia
    Huang Jing
    Dai Wei-Lin
    Fan Kang-Nian
    ACTA CHIMICA SINICA, 2008, 66 (01) : 5 - 9
  • [29] Study on Synthesis of Acid-Washed Illite Supported Fe3O4 Nanometer Catalyst and Baeyer-Villiger Oxidation Reaction of Cyclohexanone
    Yang, Yong
    Guan, Dongdong
    Liu, Yu
    Chen, Shuang
    Meng, Wan
    Jiang, Nanzhe
    CATALYSIS LETTERS, 2019, 149 (04) : 1111 - 1117
  • [30] Continuous Flow Chemo-Enzymatic Baeyer-Villiger Oxidation with Superactive and Extra-Stable Enzyme/Carbon Nanotube Catalyst: An Efficient Upgrade from Batch to Flow
    Szelwicka, Anna
    Zawadzki, Przemyslaw
    Sitko, Magdalena
    Boncel, Slawomir
    Czardybon, Wojciech
    Chrobok, Anna
    ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2019, 23 (07) : 1386 - 1395