Synthesis and crystal structure of Ca9Cu1.5(PO4)7 and reinvestigation of Ca9.5Cu(PO4)7

被引：35
|
作者：
Belik, AA [1 ]
Yanov, OV [1 ]
Lazoryak, BI [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia
来源：
MATERIALS RESEARCH BULLETIN | 2001年 / 36卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
inorganic compounds; chemical synthesis; X-ray diffraction; crystal structure;
D O I：
10.1016/S0025-5408(01)00666-3
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Ca9Cu1.5(PO4)(7) was synthesized by the solid-state method at 1273 K followed by quenching in air. Crystal structure of Ca9Cu1.5(PO4)(7) was refined by the Rietveld method: space group R3c, a = 10.3379(1) Angstrom, c = 37.1898(3) Angstrom, Z = 6 with R-wp = 4.87%, R-p = 3.67%, S = 1.58, R-I = 2.42%, R-F = 1.07%. The structure of Ca9Cu1.5(PO4)(7) is isotypic with beta -Ca-3(PO4)(2) and Ca9.5Cu(PO4)(7). The M(5) site is fully occupied, and the M(4) site is half occupied by copper canons. The M(1)-M(3) sites are occupied by calcium canons. Copper canons in the M(4) site are displaced from the threefold axis due to long distances M(4)-O. Reinvestigation of crystal structure of Ca9.5Cu(PO4)(7) showed that the M(5) site is occupied by 0.79(1)Cu2+ + 0.21Ca(2+), and other copper canons locate in the M(4) site. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1863 / 1871
页数：9
相关论文
共 50 条
  • [41] CRYSTAL-STRUCTURE OF ALPHA-CA3(PO4)2
    MATHEW, M
    SCHROEDER, LW
    DICKENS, B
    BROWN, WE
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (MAY13): : 1325 - 1333
  • [42] Thermally stimulated luminescence of Ca3(PO4)2 and Ca9Ln(PO4)7 (Ln = Pr, Eu, Tb, Dy, Ho, Er, Lu)
    Lecointre, A.
    Bessiere, A.
    Viana, B.
    Ait Benhamou, R.
    Gourier, D.
    RADIATION MEASUREMENTS, 2010, 45 (3-6) : 273 - 276
  • [43] New minerals tsangpoite Ca5(PO4)2(SiO4) and matyhite Ca9(Ca0.5□0.5)Fe(PO4)7 from the D'Orbigny angrite
    Hwang, Shyh-Lung
    Shen, Pouyan
    Chu, Hao-Tsu
    Yui, Tzen-Fu
    Varela, Maria-Euginia
    Iizuka, Yoshiyuki
    MINERALOGICAL MAGAZINE, 2019, 83 (02) : 293 - 313
  • [44] The structure of apatite (CaF)Ca-4(PO4)(3).
    Naray-Szabo, S
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1930, 75 (5/6): : 387 - 398
  • [45] Synthesis and characterization of new strontium iron (II) phosphates, SrFe2 (PO4)2 and Sr9Fe1.5 (PO4)7
    Belik, AA
    Lazoryak, BI
    Pokholok, KV
    Terekhina, TP
    Leonidov, IA
    Mitberg, EB
    Karelina, VV
    Kellerman, DG
    JOURNAL OF SOLID STATE CHEMISTRY, 2001, 162 (01) : 113 - 121
  • [46] RbZnFe(PO4)(2): synthesis and crystal structure
    Badri, Abdessalem
    Ben Amara, Mongi
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1074 - +
  • [47] THE CRYSTAL-STRUCTURE OF NA4NI7(PO4)6
    MORING, J
    KOSTINER, E
    JOURNAL OF SOLID STATE CHEMISTRY, 1986, 62 (01) : 105 - 111
  • [48] Synthesis and crystal structure of CsNb(PO4)2
    Murashova, EV
    Chudinova, NN
    CRYSTALLOGRAPHY REPORTS, 1999, 44 (06) : 955 - 957
  • [49] Synthesis and crystal structure of NaCuIn(PO4)2
    Benhsina, Elhassan
    Khmiyas, Jamal
    Ouaatta, Said
    Assani, Abderrazzak
    Saadi, Mohamed
    El Ammari, Lahcen
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2020, 76 : 366 - +
  • [50] Synthesis and crystal structure of new lead borophosphate Pb6[PO4][B(PO4)4]
    Belokoneva, EL
    Ruchkina, EA
    Dimitrova, OV
    Stefanovich, SY
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2001, 46 (02) : 179 - 185
12345