Network characteristics of hydrogenated nitrile butadiene rubber networks obtained by radiation crosslinking by electron beam

被引：18

作者：

Perraud, Sophie ^{[1
]}

Vallat, Marie-France ^{[1
]}

David, Marie-Odile ^{[2
,3
]}

Kuczynski, Jerzy ^{[3
]}

机构：

[1] Univ Haute Alsace, Inst Sci Mat Mulhouse, CNRS, LRC 7228, F-68057 Mulhouse, France

[2] IUT Evry, Val dEssonne Dept Sci & Genie Mat, F-91025 Evry, France

[3] Mac Dermid GraphicArts, F-68702 Cernay, France

来源：

POLYMER DEGRADATION AND STABILITY | 2010年 / 95卷 / 09期

关键词：

Hydrogenated nitrile butadiene rubber (HNBR); Crosslinking; Electron beam; Radiation; Mechanical properties; Network; DICUMYL PEROXIDE; ACRYLONITRILE; HNBR; IRRADIATION; COPOLYMERS; POLYMERS;

D O I：

10.1016/j.polymdegradstab.2010.06.016

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The effects of high-energy radiation on hydrogenated nitrile butadiene rubber (HNBR) copolymer structure and properties were studied. Characterization by FTIR spectroscopy, swelling and mechanical measurements of irradiated and un-irradiated sample permit us to correlate the change in structure with properties. The modifications obtained are dependent on the radiation dose of the incident electron beam. FTIR spectroscopy in absorption mode shows that irradiation of HNBR first induces trans-vinylene bond formation and secondly small amounts of carbonyl (C=O) groups. Moreover, more significant changes were observed with swelling method and mechanical behaviour showing the effect of crosslinking on the elastomer. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1495 / 1501

页数：7

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