Specificity of the reaction of tetranitromethane with alkenes in nitromethane

被引：4
|
作者：
Ivanova, O. A. [1 ]
Averina, E. B. [1 ]
Budynina, E. M. [1 ]
Korlyukov, A. A. [1 ]
Antipin, M. Yu. [1 ]
Kuznetsova, T. S. [1 ]
Zefirov, N. S. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119899, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 41卷 / 09期
基金：
俄罗斯基础研究基金会;
关键词：
Alcohol; Organic Chemistry; Alkene; Nitromethane; Tetranitromethane;
D O I：
10.1007/s11178-005-0333-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reactions of tetranitromethane with a number of di- and trisubstituted olefins in nitromethane were studied. Vinylcyclopropanes and phenylcycloalkenes reacted with tetranitromethane in an unexpected fashion, leading to formation of alkyltrinitromethanes and vicinal nitro alcohols.
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页码：1265 / 1270
页数：6
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