An experimental and kinetic modeling study of premixed nitromethane flames at low pressure

被引：58

作者：

Zhang, Kuiwen ^{[2
]}

Li, Yuyang ^{[2
]}

Yuan, Tao ^{[2
]}

Cai, Jianghuai ^{[2
]}

Glarborg, Peter ^{[1
]}

Qi, Fei ^{[2
,3
]}

机构：

[1] Tech Univ Denmark, Dept Chem & Biochem Engn, DK-2800 Lyngby, Denmark

[2] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China

[3] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China

来源：

PROCEEDINGS OF THE COMBUSTION INSTITUTE | 2011年 / 33卷

关键词：

Nitromethane; Premixed flame; Kinetic modeling; PHOTOIONIZATION CROSS-SECTIONS; SIMPLIFIED MECHANISM; FLOW REACTOR; OXIDATION; COMBUSTION; PYROLYSIS; DECOMPOSITION; DISSOCIATION; THRESHOLD; CHEMISTRY;

D O I：

10.1016/j.proci.2010.06.002

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

An experimental and modeling study is reported on three premixed nitromethane/oxygen/argon flames at low pressure (4.655 kPa) with equivalence ratios (phi) of 1.0, 1.5 and 2.0. Flame species were identified with tunable synchrotron vacuum ultraviolet photoionization. The mole fraction profiles of more than 30 species including intermediates and radicals were obtained by near-threshold burner scan with selected photon energies. With a Pt-6%Rh/Pt-30%Rh thermocouple, the flame temperature profiles were measured. A detailed kinetic mechanism with 88 species and 701 reactions was proposed and validated against experimental results of all three flames. The computed predictions showed satisfactory agreement with the experimental results. Based on a rate-of-production analysis, reaction pathway diagrams were obtained to describe the hydrocarbon oxidation process and nitrogenous species chemistry in the nitromethane flame with phi = 1.5. (C) 2010 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

引用

页码：407 / 414

页数：8

共 50 条

[21] An experimental and modeling study of humid air premixed flames
Bhargava, A
Colket, M
Sowa, W
Casleton, K
Maloney, D
[J]. JOURNAL OF ENGINEERING FOR GAS TURBINES AND POWER-TRANSACTIONS OF THE ASME, 2000, 122 (03): : 405 - 411
[22] Experimental and kinetic study on the laminar premixed cyclopentene/air flames
Zhong, Bei-jing
Zeng, Zhao-mei
[J]. FUEL, 2020, 278
[23] Experimental studies of nitromethane flames and evaluation of kinetic mechanisms
Brackmann, Christian
Naucler, Jenny D.
El-Busaidy, Said
Hosseinia, Ali
Bengtsson, Per -Erik
Konnov, Alexander A.
Nilsson, Elna J. K.
[J]. COMBUSTION AND FLAME, 2018, 190 : 327 - 336
[24] DETAILED KINETIC MODELING OF PREMIXED BENZENE FLAMES
LINDSTEDT, RP
SKEVIS, G
[J]. COMBUSTION AND FLAME, 1994, 99 (3-4) : 551 - 561
[25] Experimental and modelling study of sulfur and nitrogen doped premixed methane flames at low pressure
Hughes, KJ
Tomlin, AS
Dupont, VA
Pourkashanian, M
[J]. FARADAY DISCUSSIONS, 2001, 119 : 337 - 352
[26] Kinetic modeling study of ethanol and dimethyl ether addition to premixed low-pressure propene-oxygen-argon flames
Frassoldati, Alessio
Faravelli, Tiziano
Ranzi, Eliseo
Kohse-Hoeinghaus, Katharina
Westmoreland, Phillip R.
[J]. COMBUSTION AND FLAME, 2011, 158 (07) : 1264 - 1276
[27] Allene and Propyne Combustion in Premixed Flames: A Detailed Kinetic Modeling Study
Vourliotakis, G.
Malliotakis, Z.
Keramiotis, Ch.
Skevis, G.
Founti, M. A.
[J]. COMBUSTION SCIENCE AND TECHNOLOGY, 2016, 188 (4-5) : 776 - 792
[28] Experimental study of high-pressure turbulent premixed flames
Kobayashi, H
[J]. EXPERIMENTAL THERMAL AND FLUID SCIENCE, 2002, 26 (2-4) : 375 - 387
[29] Unraveling chemical structure of laminar premixed tetralin flames at low pressure with photoionization mass spectrometry and kinetic modeling
Li, Yuyang
Zou, Jiabiao
Yuan, Wenhao
Cao, Chuangchuang
Zhang, Yan
Qi, Fei
Yang, Jiuzhong
[J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2021, 53 (01) : 154 - 163
[30] Experimental and kinetic modeling study of ammonia addition on PAH characteristics in premixed n-heptane flames
Li, Youping
Zhang, Yiran
Zhan, Reggie
Huang, Zhen
Lin, He
[J]. FUEL PROCESSING TECHNOLOGY, 2021, 214

← 1 2 3 4 5 →