Synthesis of jet fuel range branched cycloalkanes with mesityl oxide and 2-methylfuran from lignocellulose

被引：28

作者：

Li, Shanshan ^{[1
,2
]}

Li, Ning ^{[1
,3
]}

Wang, Wentao ^{[1
]}

Li, Lin ^{[1
]}

Wang, Aiqin ^{[1
,3
]}

Wang, Xiaodong ^{[1
]}

Zhang, Tao ^{[1
,3
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 10049, Peoples R China

[3] Chinese Acad Sci, IChEM Collaborat Innovat Ctr Chem Energy Material, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

SCIENTIFIC REPORTS | 2016年 / 6卷

基金：

中国国家自然科学基金;

关键词：

CATALYTIC CONVERSION; LIQUID ALKANES; METHYL KETONES; BIOMASS; CYCLOPENTANONE; CONDENSATION; DIESEL; ACID; FERMENTATION; BUTANOL;

D O I：

10.1038/srep32379

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Jet fuel range branched cycloalkanes with high density (0.82 g mL(-1)) and low freezing point (217-219 K) was first prepared by the solvent-free intramolecular aldol condensation of the trione from the hydrolysis of the alkylation product of mesityl oxide and 2-methylfuran (or the one-pot reaction of mesityl oxide, 2-methylfuran and water), followed by hydrodeoxygenation (HDO).

引用

页数：7

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