Rhodium(III)-catalyzed aromatic C-H cyanation with dimethylmalononitrile as a cyanating agent

被引：21

作者：

Li, He ^{[1
]}

Zhang, Sheng ^{[1
]}

Yu, Xiaoqiang ^{[1
]}

Feng, Xiujuan ^{[1
]}

Yamamoto, Yoshinori ^{[1
,3
,4
]}

Bao, Ming ^{[1
,2
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116023, Peoples R China

[2] Dalian Univ Technol, Sch Petr & Chem Engn, Panjin 124221, Peoples R China

[3] Tohoku Univ, WPI Adv Inst Mat Res, Sendai, Miyagi 9808577, Japan

[4] Ritsumeikan Univ, Res Org Sci & Technol, Kusatsu, Shiga 5258577, Japan

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 09期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

RHODIUM-CATALYZED CYANATION; LITHIUM REAGENTS; ARENES; BOND; TRANSNITRILATION; CHLORIDES; NITRILES; GRIGNARD; HALIDES; CARBON;

D O I：

10.1039/c8cc08930b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A rhodium-catalyzed aromatic C-H bond direct cyanation with safe, bench-stable, and commercially available dimethylmalononitrile as the cyanating agent has been successfully developed by using copper oxide as a promotor. Pyridine, quinoline, pyrimidine and pyrazole were used as the directing group in this type of C-H bond direct cyanation reaction.

引用

页码：1209 / 1212

页数：4

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