Construction of two- and three-dimensional coordination polymers from cobalt trimesate

被引：120
|
作者：
Livage, C [1 ]
Guillou, N [1 ]
Marrot, J [1 ]
Férey, G [1 ]
机构：
[1] Univ Versailles, Inst Lavoisier, UMR CNRS 8637, F-78035 Versailles, France
来源：
CHEMISTRY OF MATERIALS | 2001年 / 13卷 / 11期
关键词：
D O I：
10.1021/cm011115k
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two new cobalt 1,3,5-benzenetricarboxylate (trimesic acid, TMA) coordination polymers were synthesized and structurally characterized: [Co-3(H2O)(6)(TMA(3-))(TMA(2-))(TMA(1-))]. 2H(2)O (1) and K[Co-3(TMA(3-))(TMA(2-))(2)]. 5H(2)O (2). 1 crystallizes in the hexagonal system, space group P6(5)22 (no. 179), with a = 16.7265(2), c = 20.5822(4) Angstrom, V = 4986.9(2) Angstrom (3), and D-c = 1.889 g cm 3. 2 is monoclinic, space group P2/c (no. 13), with a = 9.6096(1), b = 12.5610(1), c = 13.9736(2) Angstrom, beta = 109.239(1)degrees, V = 1592.50(3) Angstrom (3), and D-c = 1.938 g cm(-3). 1 is two-dimensional and formed by a "dense" stacking of {Co-3(H2O)(6)(TMA(3-))(TMA(2-))(TMA(1-))} layers. In compound 2 the connection of sinusoidal chains of cobalt octahedra by two types of trimesate ions gives a three-dimensional network with pentahydrated channels.
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收藏
页码：4387 / 4392
页数：6
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