P,C-bond cleavage in the ligand sphere of a nickel(II) complex

被引：2

作者：

Walg, Simon P. ^{[1
]}

Schmidt, Alexandra D. ^{[1
]}

Schmitz, Marcus ^{[1
]}

Farsadpour, Saeid ^{[1
]}

Lang, Johannes ^{[1
]}

Niebergall, Mark ^{[1
]}

Sun, Yu ^{[1
]}

Roesky, Peter W. ^{[2
]}

Niedner-Schatteburg, Gereon ^{[1
]}

Thiel, Werner R. ^{[1
]}

机构：

[1] Tech Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany

[2] Karlsruhe Inst Technol, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 03期

关键词：

CROSS-COUPLING REACTION; CARBON-PHOSPHORUS BOND; MOLECULAR-STRUCTURE; PINCER COMPLEXES; ALKYL-HALIDES; LINEAR OLIGOMERIZATION; EFFICIENT SYNTHESIS; CRYSTAL-STRUCTURES; GRIGNARD-REAGENTS; CLUSTER CHEMISTRY;

D O I：

10.1039/c4dt02158d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reacting nickel(II) perchlorate with a bidentate P,N-ligand in methanol leads to P,C-bond cleavage and gives a five-coordinate nickel complex wherein the nickel(II) site is coordinated by a tridentate P,N,P-ligand and a bidentate N,C-ligand. The carbanion of the latter is the result of the P,C-bond cleaving process. The diamagnetic nickel(II) complex was characterized by means of elemental analysis, NMR spectroscopy, cyclic voltammetry and X-ray structure analysis.

引用

页码：1317 / 1322

页数：6

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