P,C-bond cleavage in the ligand sphere of a nickel(II) complex

被引：2

作者：

Walg, Simon P. ^{[1
]}

Schmidt, Alexandra D. ^{[1
]}

Schmitz, Marcus ^{[1
]}

Farsadpour, Saeid ^{[1
]}

Lang, Johannes ^{[1
]}

Niebergall, Mark ^{[1
]}

Sun, Yu ^{[1
]}

Roesky, Peter W. ^{[2
]}

Niedner-Schatteburg, Gereon ^{[1
]}

Thiel, Werner R. ^{[1
]}

机构：

[1] Tech Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany

[2] Karlsruhe Inst Technol, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 03期

关键词：

CROSS-COUPLING REACTION; CARBON-PHOSPHORUS BOND; MOLECULAR-STRUCTURE; PINCER COMPLEXES; ALKYL-HALIDES; LINEAR OLIGOMERIZATION; EFFICIENT SYNTHESIS; CRYSTAL-STRUCTURES; GRIGNARD-REAGENTS; CLUSTER CHEMISTRY;

D O I：

10.1039/c4dt02158d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reacting nickel(II) perchlorate with a bidentate P,N-ligand in methanol leads to P,C-bond cleavage and gives a five-coordinate nickel complex wherein the nickel(II) site is coordinated by a tridentate P,N,P-ligand and a bidentate N,C-ligand. The carbanion of the latter is the result of the P,C-bond cleaving process. The diamagnetic nickel(II) complex was characterized by means of elemental analysis, NMR spectroscopy, cyclic voltammetry and X-ray structure analysis.

引用

页码：1317 / 1322

页数：6

共 50 条

[1] REDUCTIVE CLEAVAGE OF THE CO,C-BOND OF [(METHOXYCARBONYL)METHYL]COBALAMIN
TINEMBART, O
WALDER, L
SCHEFFOLD, R
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1988, 92 (11): : 1225 - 1231
[2] Formation of a nickel(II) complex with a new N2S2 macrocyclic ligand by C-Cl bond cleavage and C-S bond formation
Kawamoto, T
Kuma, H
Kushi, Y
CHEMICAL COMMUNICATIONS, 1996, (18) : 2121 - 2122
[3] MEDIUM EFFECTS ON C,C-BOND CLEAVAGE IN THE ALCOHOL OXIDATION WITH CHROMIC-ACID
MULLER, P
BLANC, J
HELVETICA CHIMICA ACTA, 1979, 62 (06) : 1980 - 1984
[4] FACILE CLEAVAGE OF A C-C BOND IN A DINUCLEAR NICKEL-COMPLEX
LAWRIE, CJ
DANKOSH, HE
CARPENTER, BK
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 411 (1-2) : C7 - C10
[5] Ligand cleavage put into reverse: P-C bond breaking and remaking in an alkylphosphane iron complex
Kohl, Stephan W.
Heinemann, Frank W.
Hummert, Markus
Bauer, Walter
Grohmann, Andreas
CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (16) : 4313 - 4320
[6] C-C bond cleavage of acetonitrile by a carbonyl iron complex with a silyl ligand
Nakazawa, H
Kawasaki, T
Miyoshi, K
Suresh, CH
Koga, N
ORGANOMETALLICS, 2004, 23 (01) : 117 - 126
[7] ALKALI-METAL INDUCED C,C-BOND CLEAVAGE, C,H-BOND CLEAVAGE, AND CYCLO-POLYMERIZATION IN 1,5-HEXADIENES
TRINKS, R
MULLEN, K
TETRAHEDRON LETTERS, 1988, 29 (32) : 3929 - 3930
[8] Synthesis and characterization of palladium (II) complex of Schiff base ligand: C-S bond cleavage and catalytic activity
Pattanayak, Poulami
Patra, Debprasad
Brandao, Paula
Mal, Dasarath
Felix, Vitor
INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 53 : 68 - 71
[9] A ruthenium(II) complex having a ligand undergoing partial C = N cleavage and unusual double-bond shift and nonchirality
Geng, Jiao
Zhang, Kun
Peng, Yu-Xin
Wang, Li
Huang, Wei
INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 40 : 112 - 115
[10] Synthesis, crystal structure, and DNA cleavage activity of a dinuclear nickel(II) complex with a macrocyclic ligand
Hong Hu
Yunfeng Chen
Hong Zhou
Zhiquan Pan
Transition Metal Chemistry, 2011, 36 : 395 - 402

← 1 2 3 4 5 →