Improved ethanol gas-sensing properties of optimum Fe-ZnO mesoporous nanoparticles

被引:6
|
作者
Shen, Yue [1 ]
Li, Qinyi [1 ]
Li, Tai [1 ]
Cao, Meng [1 ]
Gu, Feng [1 ]
Wang, Linjun [1 ]
Zhu, Da-Ming [2 ]
机构
[1] Shanghai Univ, Sch Materials Sci, Engn, Shanghai, Shanghai, Peoples R China
[2] Univ Missouri, Dept Phys, Astronomy, Kansas City, MO 64110 USA
基金
中国国家自然科学基金;
关键词
PERFORMANCE; FABRICATION; FILMS; NANOSTRUCTURES; NANOSHEETS; NANOWIRES; MECHANISM; NANORODS; SN;
D O I
10.1007/s10854-019-02852-2
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Fe-doped ZnO (Fe-ZnO) mesoporous nanoparticles have been synthesized via a facile hydrothermal method, which utilizes pluronic triblock copolymer polyethylene glycol-polypropylene glycol-polyethylene glycol (PEO-PPO-PEO) as the pore-forming agent. Fe-ZnO composites have an unique porous structure. Their pore sizes increase with Fe-doping concentration and reach a maximum as Fe concentration is 15 at.%; the specific surface area of synthesized mesoporous Fe-ZnO nanoparticles reaches a maximum as the Fe concentration is about 11 at.%. Electron microscopy, vapor pressure isotherm measurements and photoluminescence (PL) were used to characterize synthesized Fe-ZnO composites. Fe-ZnO-based gas sensors exhibit excellent response in detecting ethanol; the sensing response of Fe(11 at.%)-ZnO reaches 319.8, which is significantly higher than most of the ZnO-based gaseous sensors. The improved sensitivity is ascribed to the increase of oxygen-related defects and specific surface area of Fe-ZnO composites.
引用
收藏
页码:3074 / 3083
页数:10
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