Structural and NMR spectroscopic characterization of ferrocene-containing eta(3)-allylpalladium complexes

被引：5

作者：

Wu, YJ ^{[1
]}

Liu, YH ^{[1
]}

Yuan, HZ ^{[1
]}

Mao, XA ^{[1
]}

机构：

[1] ACAD SINICA,WUHAN INST PHYS,LAB MAGNET RESONANCE & ATOM & MOLEC PHYS,WUHAN 430071,PEOPLES R CHINA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 519卷 / 1-2期

关键词：

eta(3)-allylpalladium complex; ferrocene; palladium; crystal structure;

D O I：

10.1016/S0022-328X(96)06232-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 1,3-diferrocenylbut-2-en-1-one 1 with Li2PdCl4 in methanol in the presence of NaOAc produced mu-chloro-bridged eta(3)-allylpalladium complex 2 in high yield. Treatment of 2 with PPh(3) afforded the monomeric triphenylphosphine derivative 3. The anti conformation of 3 was confirmed by 2D H-1 NMR spectroscopy and also by X-ray crystallography.

引用

页码：237 / 242

页数：6

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