Structural and NMR spectroscopic characterization of ferrocene-containing eta(3)-allylpalladium complexes

被引：5
|
作者：
Wu, YJ [1 ]
Liu, YH [1 ]
Yuan, HZ [1 ]
Mao, XA [1 ]
机构：
[1] ACAD SINICA,WUHAN INST PHYS,LAB MAGNET RESONANCE & ATOM & MOLEC PHYS,WUHAN 430071,PEOPLES R CHINA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 519卷 / 1-2期
关键词：
eta(3)-allylpalladium complex; ferrocene; palladium; crystal structure;
D O I：
10.1016/S0022-328X(96)06232-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of 1,3-diferrocenylbut-2-en-1-one 1 with Li2PdCl4 in methanol in the presence of NaOAc produced mu-chloro-bridged eta(3)-allylpalladium complex 2 in high yield. Treatment of 2 with PPh(3) afforded the monomeric triphenylphosphine derivative 3. The anti conformation of 3 was confirmed by 2D H-1 NMR spectroscopy and also by X-ray crystallography.
引用
收藏
页码：237 / 242
页数：6
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