Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C-H/C-O Cleavage

被引：83

作者：

Moselage, Marc ^{[1
]}

Sauermann, Nicolas ^{[1
]}

Koeller, Julian ^{[1
]}

Liu, Weiping ^{[1
]}

Gelman, Dmitri ^{[2
]}

Ackermann, Lutz ^{[1
]}

机构：

[1] Univ Gottingen, Inst Organ & Biomol Chem, D-37077 Gottingen, Germany

[2] Hebrew Univ Jerusalem, Inst Chem, IL-91904 Jerusalem, Israel

来源：

SYNLETT | 2015年 / 26卷 / 11期

基金：

欧洲研究理事会;

关键词：

allylation; C-H activation; C-O cleavage; cobalt; heteroarene; H BOND ACTIVATION; CATALYZED DIRECT ARYLATION; N-TYPE REACTIONS; ARENES; ALKYLATIONS; CYANATION; FUNCTIONALIZATIONS; (HETERO)ARENES; HETEROARENES; CARBOXYLATE;

D O I：

10.1055/s-0034-1379927

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Versatile cobalt-catalyzed C-H allylations on arenes, indoles, and pyrroles were accomplished with allyl acetates. The C-H/C-O functionalization process was characterized by a broad substrate scope as well as an excellent functional-group tolerance and was shown to occur by initial C-H cobaltation.

引用

页码：1596 / 1600

页数：5

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