Facile synthesis of high-surface-area nanoporous carbon from biomass resources and its application in supercapacitors

被引:16
|
作者
Yao, Yuechao [1 ]
Zhang, Qi [3 ]
Liu, Peng [1 ]
Yu, Liang [1 ]
Huang, Lin [1 ,2 ]
Zeng, Shao-Zhong [1 ,2 ]
Liu, Lijia [1 ,2 ]
Zeng, Xierong [1 ]
Zou, Jizhao [1 ]
机构
[1] Shenzhen Univ, Coll Mat Sci & Engn, Shenzhen Engn Lab Adv Technol Ceram, Shenzhen Key Lab Special Funct Mat, Shenzhen 518060, Peoples R China
[2] Shenzhen Univ, Coll Optoelect Engn, Minist Educ & Guangdong Prov, Key Lab Optoelect Devices & Syst, Shenzhen 518060, Peoples R China
[3] Cranfield Univ, Sch Aerosp Transport & Mfg, Cranfield MK43 0AL, Beds, England
来源
RSC ADVANCES | 2018年 / 8卷 / 04期
基金
中国国家自然科学基金;
关键词
HIGH-PERFORMANCE SUPERCAPACITOR; ELECTRODE MATERIALS; SULFUR BATTERIES; ACTIVATED CARBON; KOH ACTIVATION; POROUS CARBONS; NANOFIBERS; NANOSHEETS; MICROSPHERES; NETWORK;
D O I
10.1039/c7ra12525a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
It is critical for nanoporous carbons to have a large surface area, and low cost and be readily available for challenging energy and environmental issues. The pursuit of all three characteristics, particularly large surface area, is a formidable challenge because traditional methods to produce porous carbon materials with a high surface area are complicated and expensive, frequently resulting in pollution (commonly from the activation process). Here we report a facile method to synthesize nanoporous carbon materials with a high surface area of up to 1234 m(2) g(-1) and an average pore diameter of 0.88 nm through a simple carbonization procedure with carefully selected carbon precursors (biomass material) and carbonization conditions. It is the high surface area that leads to a high capacitance (up to 213 F g(-1) at 0.1 A g(-1)) and a stable cycle performance (6.6% loss over 12 000 cycles) as shown in a three-electrode cell. Furthermore, the high capacitance (107 F g(-1) at 0.1 A g(-1)) can be obtained in a supercapacitor device. This facile approach may open a door for the preparation of high surface area porous carbons for energy storage.
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页码:1857 / 1865
页数:9
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