Synthesis and pore size control of cubic mesoporous silica SBA-1

被引:185
|
作者
Kim, MJ
Ryoo, R [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem, Mat Chem Lab, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, Ctr Mol Sci, Taejon 305701, South Korea
关键词
D O I
10.1021/cm980691m
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The formation of silica-surfactant mesostructures has been studied under various acidic conditions using tetraethyl orthosilicate and hexadecyltriethylammonium bromide. The synthesis conditions have been optimized in order to obtain the cubic (PmSn) mesoporous molecular sieve designated as SBA-1 of high quality. The pore diameter of the SBA-1 material has been controlled within the range of 1.4-2.7 nm by expanding the surfactant micelles with 1,3,5-trimethylbenzene or substituting the hexadecyl group of the surfactant with other n-alkyl groups (C12H25 to C18H37).
引用
收藏
页码:487 / 491
页数:5
相关论文
共 50 条
  • [21] Phase control of cubic SBA-1 mesostructures via alcohol-assisted synthesis
    Kao, HM
    Cheng, CC
    Ting, CC
    Hwang, LY
    JOURNAL OF MATERIALS CHEMISTRY, 2005, 15 (29) : 2989 - 2992
  • [22] Grafting of magnesium and yttrium silylamides onto periodic mesoporous silica SBA-1
    Zapilko, C
    Anwander, R
    MOLECULAR SIEVES: FROM BASIC RESEARCH TO INDUSTRIAL APPLICATIONS, PTS A AND B, 2005, 158 : 461 - 468
  • [23] pH responsive selective protein adsorption by carboxylic acid functionalized large pore mesoporous silica nanoparticles SBA-1
    Saikia, Diganta
    Deka, Juti Rani
    Wu, Cheng-En
    Yang, Yung-Chin
    Kao, Hsien-Ming
    MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2019, 94 : 344 - 356
  • [24] Microwave synthesis of cubic mesoporous silica SBA-16
    Hwang, YK
    Chang, JS
    Kwon, YU
    Park, SE
    MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 68 (1-3) : 21 - 27
  • [25] Structural aspects of SBA-1 cubic mesoporous silica synthesized via a sol-gel process using a silatrane precursor
    Tanglumlert, Walairat
    Imae, Toyoko
    White, Timothy J.
    Wongkasemjit, Sujitra
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2007, 90 (12) : 3992 - 3997
  • [26] Ru Nanoparticles Embedded in Cubic Mesoporous Silica SBA-1 as Highly Efficient Catalysts for Hydrogen Generation from Ammonia Borane
    Deka, Juti Rani
    Saikia, Diganta
    Hsia, Kuo-Shu
    Kao, Hsien-Ming
    Yang, Yung-Chin
    Chen, Ching-Shiun
    CATALYSTS, 2020, 10 (03)
  • [27] Postfunctionalization of periodic mesoporous silica SBA-1 with magnesium(II) and iron(II) silylamides
    Deschner, Thomas
    Klimpel, Michael
    Tafipolsky, Maxim
    Scherer, Wolfgang
    Tornroos, Karl W.
    Anwander, Reiner
    DALTON TRANSACTIONS, 2012, 41 (24) : 7319 - 7326
  • [28] Whispering gallery modes in highly hexagonal symmetric structures of SBA-1 mesoporous silica
    Chen, C. W.
    Chen, Y. F.
    APPLIED PHYSICS LETTERS, 2007, 90 (07)
  • [29] Direct synthesis of V-incorporated SBA-1 mesoporous molecular sieves
    Dai, LX
    Tabata, K
    Suzuki, E
    Tatsumi, T
    JOURNAL OF MATERIALS SCIENCE LETTERS, 2000, 19 (23) : 2071 - 2073
  • [30] Tetramethoxysilane as a convenient silicon source for phase control of cubic SBA-1 mesostructures
    Kao, Hsien-Ming
    Cheng, Chung-Chih
    MATERIALS LETTERS, 2006, 60 (21-22) : 2594 - 2599