Synthesis and pore size control of cubic mesoporous silica SBA-1

被引:185
|
作者
Kim, MJ
Ryoo, R [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem, Mat Chem Lab, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, Ctr Mol Sci, Taejon 305701, South Korea
关键词
D O I
10.1021/cm980691m
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The formation of silica-surfactant mesostructures has been studied under various acidic conditions using tetraethyl orthosilicate and hexadecyltriethylammonium bromide. The synthesis conditions have been optimized in order to obtain the cubic (PmSn) mesoporous molecular sieve designated as SBA-1 of high quality. The pore diameter of the SBA-1 material has been controlled within the range of 1.4-2.7 nm by expanding the surfactant micelles with 1,3,5-trimethylbenzene or substituting the hexadecyl group of the surfactant with other n-alkyl groups (C12H25 to C18H37).
引用
收藏
页码:487 / 491
页数:5
相关论文
共 50 条
  • [1] Pore size engineering and mechanical stability of the cubic mesoporous molecular sieve SBA-1
    Vinu, A
    Murugesan, V
    Hartmann, M
    CHEMISTRY OF MATERIALS, 2003, 15 (06) : 1385 - 1393
  • [2] Direct synthesis of vinyl-functionalized cubic mesoporous silica SBA-1
    Kao, HM
    Wu, JD
    Cheng, CC
    Chiang, AST
    MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 88 (1-3) : 319 - 328
  • [3] Sugar-Assisted Synthesis of Ordered and Stable Cubic Mesoporous Silica SBA-1
    Ting, Chun-Chiang
    Wu, Hao-Yiang
    Pan, Yu-Chi
    Vetrivel, Shanmugam
    Fey, George T. K.
    Kao, Hsien-Ming
    JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (45): : 19322 - 19330
  • [4] Synthesis of cubic mesoporous silica SBA-1 with bulky headgroup surfactant cetyltripropylammonium bromide
    Kao, Hsien-Ming
    Liao, Yun-Wun
    Ting, Chun-Chiang
    MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 98 (1-3) : 80 - 88
  • [5] Control of crystal morphology of SBA-1 mesoporous silica
    Che, S
    Sakamoto, Y
    Terasaki, O
    Tatsumi, T
    CHEMISTRY OF MATERIALS, 2001, 13 (07) : 2237 - +
  • [6] Synthesis of SBA-1 mesoporous silica crystals with tunable pore size using sodium silicate and alkyltrimethylammonium surfactants
    Chao, MC
    Lin, HP
    Wang, DS
    Mon, CY
    CHEMISTRY LETTERS, 2004, 33 (04) : 374 - 375
  • [7] Control of single crystal morphology of SBA-1 mesoporous silica
    Chao, MC
    Wang, DS
    Lin, HP
    Mou, CY
    JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (12) : 2853 - 2854
  • [8] Control of ordered structure and morphology of cubic mesoporous silica SBA-1 via direct synthesis of thiol-functionalization
    Kao, Hsien-Ming
    Shen, Tzu-Yi
    Wu, Jyun-Da
    Lee, Lung-Ping
    MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 110 (2-3) : 461 - 471
  • [9] Synthesis and morphology control of SBA-1 mesoporous silica with surfactant of cetyltrimethylammonium bromide (CTMABr)
    Che, S
    Sakamoto, Y
    Terasaki, O
    Tatsumi, T
    CHEMISTRY LETTERS, 2002, (02) : 214 - 215
  • [10] Mn-incorporated SBA-1 cubic mesoporous silicates: Synthesis and characterization
    Imran, Gaffar
    Maheswari, Rajamanickam
    MATERIALS CHEMISTRY AND PHYSICS, 2015, 161 : 237 - 242