New complexes of 3,4-dimethoxyphenylacetic acid with selected transition metal ions: Spectral, thermal, and magnetic properties

被引：0

作者：

Ferenc, W. ^{[1
]}

Osypiuk, D. ^{[1
]}

Cristovao, B. ^{[1
]}

Sarzynski, J. ^{[2
]}

Gluchowska, H. ^{[1
]}

机构：

[1] Marie Curie Sklodowska Univ, Fac Chem, PL-20031 Lublin, Poland

[2] Marie Curie Sklodowska Univ, Inst Phys, PL-20031 Lublin, Poland

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2017年 / 87卷 / 09期

关键词：

3,4-dimethoxyphenylacetic acid; transition metals; magnetic properties; thermal stability; powder diffraction; OXYGEN STRETCHING FREQUENCIES; CARBOXYLATE COORDINATION; CRYSTAL-STRUCTURE; CU(II) COMPLEXES; 1,10-PHENANTHROLINE; DIMETHOXYPHENYLETHYLAMINE; TETRAHYDROPAPAVERINE;

D O I：

10.1134/S1070363217090213

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3,4-Dimethoxyphenylacetates of Mn(II), Co(II), Ni(II), Cu(II), and Zn(II) of general formula M(C10H11O4)(2)center dot nH(2)O, where n = 1, 2 or 4 depending on M(II) ions, are obtained. The complexes crystallize in monoclinic or triclinic systems. The carboxylate groups act as bidentate chelating or bridging ligands. On heating in the air (293-1173 K) they decompose in three steps finally forming oxides of the corresponding metals(II) or their mixtures. Magnetic moments of compounds were determined in the ranges of 76-303 and 4-300 K.

引用

页码：2045 / 2055

页数：11

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