A novel technique to determine the rate constants for the gas-phase reactions of low-volatile compounds with OH radical using a relative-rate method in CCl4 liquid phase-system

被引：5

作者：

Kameda, T

Asano, K

Inazu, K

Hisamatsu, Y

Takenaka, N

Bandow, H

机构：

[1] Osaka Prefecture Univ, Dept Appl Mat Sci, Sakai, Osaka 5998531, Japan

[2] Tokyo Inst Technol, Frontier Collaborat Res Ctr, Midori Ku, Yokohama, Kanagawa 2268503, Japan

[3] Natl Inst Publ Hlth, Minato Ku, Tokyo 1088638, Japan

来源：

CHEMISTRY LETTERS | 2005年 / 34卷 / 06期

关键词：

D O I：

10.1246/cl.2005.758

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For low-volatile aromatic compounds, a good linear relationship was found between the rate-constant ratio for the liquid-phase reaction with NO3 radical in CCl4 and that for the gas-phase reaction with OH radical when naphthalene was employed as a reference compound. Based on the relationship, the rate constants for the OH radical reaction have been successfully determined for fluoranthene and pyrene, which are important airborne polycyclic aromatic compounds.

引用

页码：758 / 759

页数：2

共 33 条

[21] Kinetic study of OH radical reactions with volatile organic compounds using relative rate/discharge fast flow/mass spectrometer technique
Li, ZJ
CHEMICAL PHYSICS LETTERS, 2004, 383 (5-6) : 592 - 600
[22] A novel small-ratio relative-rate technique for measuring OH formation yields from the reactions of O3 with alkenes in the gas phase, and its application to the reactions of ethene and propene
Paulson, SE
Fenske, JD
Sen, AD
Callahan, TW
JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (13): : 2050 - 2059
[23] RATE CONSTANTS FOR THE GAS-PHASE REACTIONS OF THE NO3 RADICAL WITH A SERIES OF ORGANIC-COMPOUNDS AT 296+/-2-K
ATKINSON, R
ASCHMANN, SM
PITTS, JN
JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (12): : 3454 - 3457
[24] RATE CONSTANTS FOR THE GAS-PHASE REACTIONS OF THE OH RADICAL WITH DICHLOROBIPHENYLS, 1-CHLORODIBENZO-P-DIOXIN, 1,2-DIMETHOXYBENZENE, AND DIPHENYL ETHER - ESTIMATION OF OH RADICAL REACTION-RATE CONSTANTS FOR PCBS, PCDDS, AND PCDFS
KWOK, ESC
ATKINSON, R
AREY, J
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1995, 29 (06) : 1591 - 1598
[25] Geraniol (2,6-dimethyl-2,6-octadien-8-ol) reactions with ozone and OH radical: Rate constants and gas-phase products
Forester, Crystal D.
Ham, Jason E.
Wells, J. R.
ATMOSPHERIC ENVIRONMENT, 2007, 41 (06) : 1188 - 1199
[26] ESTIMATING GAS-PHASE RATE CONSTANTS FOR REACTIONS OF ORGANIC-COMPOUNDS WITH HYDROXYL RADICALS FROM RELATIVE RATES MEASURED IN CF2CLCFCL2 SOLUTION - A METHOD FOR ESTIMATING THE TROPOSPHERIC PERSISTENCE OF COMPOUNDS DIFFICULT TO STUDY IN THE GAS-PHASE
DILLING, WL
GONSIOR, SJ
BOGGS, GU
MENDOZA, CG
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 192 : 18 - ENVR
[27] Rate constants for the gas-phase reactions of O3/ with a series of terpenes and OH radical formation from the O$-3 reactions with sesquiterpenes at 296 &plusmn 2 K
1600, John Wiley & Sons Inc, New York, NY, USA (26):
[28] ESTIMATION OF HYDROXYL RADICAL REACTION-RATE CONSTANTS FOR GAS-PHASE ORGANIC-COMPOUNDS USING A STRUCTURE-REACTIVITY RELATIONSHIP - AN UPDATE
KWOK, ESC
ATKINSON, R
ATMOSPHERIC ENVIRONMENT, 1995, 29 (14) : 1685 - 1695
[29] RATE CONSTANTS FOR THE GAS-PHASE REACTIONS OF O-3 WITH A SERIES OF TERPENES AND OH RADICAL FORMATION FROM THE O-3 REACTIONS WITH SESQUITERPENES AT 296+/-2-K
SHU, YG
ATKINSON, R
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1994, 26 (12) : 1193 - 1205
[30] RATE CONSTANTS FOR THE GAS-PHASE REACTIONS OF THE OH RADICAL WITH CF3CF2CHCL2 (HCFC-225CA) AND CF2CLCF2CHCLF (HCFC-225CB)
ZHANG, ZY
LIU, RH
HUIE, RE
KURYLO, MJ
GEOPHYSICAL RESEARCH LETTERS, 1991, 18 (01) : 5 - 7

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