Synthesis of 2,6-dialkoxylphenyllanthanoid complexes and their polymerization catalysis

被引：19

作者：

Ihara, E

Adachi, Y

Yasuda, H ^{[1
]}

Hashimoto, H

Kanehisa, N

Kai, Y

机构：

[1] Hiroshima Univ, Fac Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan

[2] Osaka Univ, Fac Engn, Dept Appl Chem, Yamadaoka 5650871, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 569卷 / 1-2期

关键词：

tri(phenyl)samarium; polymerization catalyst; methyl methacrylate; epsilon-caprolactone; hexyl isocyanate; butyl isocyanate; rare earth metal compound;

D O I：

10.1016/S0022-328X(98)00783-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1:1-2:1 reaction of [2,6-((PrO)-Pr-i)(2)C6H3]Li with anhydrous SmCl3 in THF gave [2,6-((PrO)-Pr-i)(2)C6H3](3) Sm 1 exclusively, while the 3:1 reaction gave [2,6-((PrO)-Pr-i)(2)C6H3](4)SmLi 2 as major product, which crystallizes in the monoclinic space group C2/c(No. 15) with a = 47.52(1) Angstrom, b = 11.680(9) Angstrom, c = 18.862(9) Angstrom, beta = 112.19(3)degrees, V= 9694(8) Angstrom(3), Z = 8, R = 0.077 and R-w = 0.074. In a similar manner, [2,6-((PrO)-Pr-i)(2)C6H3](3)La was obtained by reacting with LaCl3(THF)(2). The 2:1 reaction of [2,6-((PrO)-Pr-i)(2)C6H3]Li with YbCl3 gave [2,6-((PrO)-Pr-i)(2)C6H3](2)YbCl, which produces [2,6-((PrO)-Pr-i)(2)C6H3]Yb-2[CH(SiMe3)(2)](2)Li 4 by reaction with (SiMe3)(2)CHLi. Polymerizations of epsilon-caprolactone and alkyl isocyanates were examined using the resulting complexes. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：147 / 157

页数：11

共 50 条

[41] Synthesis and Structural Analysis of (Cyclopentadienyl)(pyrrolide)titanium(IV) Complexes and Their Use in Catalysis for Olefin Polymerization
Saeed, Irfan
Katao, Shohei
Nomura, Kotohiro
ORGANOMETALLICS, 2009, 28 (01) : 111 - 122
[42] Borane and Borohydride Complexes of the Rare-Earth Elements: Synthesis, Structures, and Butadiene Polymerization Catalysis
Jenter, Jelena
Meyer, Nils
Roesky, Peter W.
Thiele, Sven K. -H.
Eickerling, Georg
Scherer, Wolfgang
CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (18) : 5472 - 5480
[43] (Pentamethylcyclopentadienyl)lanthanide(II) alkyl and silyl complexes: Synthesis, structures, and catalysis in polymerization of ethylene and styrene
Hou, ZM
Zhang, Y
Nishiura, M
Wakatsuki, Y
ORGANOMETALLICS, 2003, 22 (01) : 129 - 135
[44] Synthesis and Characterization of Heteroscorpionate Rare-Earth Metal Dialkyl Complexes and Catalysis on MMA Polymerization
Zhang, Zhichao
Cui, Dongmei
Trifonov, Alexander A.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (18) : 2861 - 2866
[45] Mixed ligands supported yttrium alkyl complexes: Synthesis, characterization and catalysis toward lactide polymerization
Miao, Wei
Li, Shihui
Zhang, Hongxia
Cui, Dongmei
Wang, Yurong
Huang, Baotong
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (22) : 4828 - 4834
[46] Non-bridged amido cyclopentadienyl complexes of titanium: synthesis, characterization, and olefin polymerization catalysis
Sinnema, PJ
Spaniol, TP
Okuda, J
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 598 (01) : 179 - 181
[47] Synthesis, Structural Characterization, Enzymatic and Oxidative Polymerization of 2,6-Diaminopyridine
Dilek Şenol
Journal of Fluorescence, 2020, 30 : 157 - 174
[48] POLYMERIZATION OF 2,6-DIARYLPHENOLS
HAY, AS
DANA, DE
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (03) : 873 - 880
[49] Polymerization of 2,6-diarylphenols
Hay, A.S., 1600, (27):
[50] Polymerization catalysis with transition metal amidinate and related complexes
Collins, Scott
COORDINATION CHEMISTRY REVIEWS, 2011, 255 (1-2) : 118 - 138

← 1 2 3 4 5 →