N-Formylation of Amines Catalyzed by Nanogold under Aerobic Oxidation Conditions with MeOH or Forma

被引:64
|
作者
Preedasuriyachai, Patcharee [2 ]
Kitahara, Hiroaki [1 ]
Chavasiri, Warinthorn [3 ]
Sakurai, Hidehiro [1 ,4 ]
机构
[1] Inst Mol Sci, Res Ctr Mol Scale Nanosci, Okazaki, Aichi 4448787, Japan
[2] Chulalongkorn Univ, Fac Sci, Program Petrochem & Polymer Sci, Bangkok 10330, Thailand
[3] Chulalongkorn Univ, Fac Sci, Dept Chem, Bangkok 10330, Thailand
[4] Japan Sci & Technol Agcy, PRESTO, Tokyo 1020075, Japan
关键词
GOLD NANOCLUSTERS; INTRAMOLECULAR ADDITION; UNACTIVATED ALKENES; HYDROGEN-PEROXIDE; AMIDE SYNTHESIS; ALCOHOLS; AMIDATION; ALDEHYDES; METHANOL; ACID;
D O I
10.1246/cl.2010.1174
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Gold nanoclusters stabilized by poly(N-vinyl-2-pyrrolidone) (Au PVP) are active and selective catalysts for N-formylation of amines under aerobic oxidation using methanol or formalin as a formyl source
引用
收藏
页码:1174 / 1176
页数:3
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