Briarane, erythrane, and aquariane diterpenoids from the Caribbean gorgonian Erythropodium caribaeorum

被引：12
|
作者：
Taglialatela-Scafati, O
Craig, KS
Rebérioux, D
Roberge, M
Andersen, RJ
机构：
[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada
[2] Univ British Columbia, Dept Earth & Ocean Sci, Vancouver, BC V6T 1Z1, Canada
[3] Univ Naples Federico II, Dipartimento Chim Sostanze Nat, I-80131 Naples, Italy
[4] Univ British Columbia, Dept Biochem & Mol Biol, Vancouver, BC V6T 1Z1, Canada
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 2003卷 / 18期
关键词：
natural products; terpenoids; structure elucidation; asymmetric synthesis; bioorganic chemistry;
D O I：
10.1002/ejoc.200300214
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Seven new diterpenoids belonging to the briarane [erythrolides R (5), S (6), T (7), and U (8)], erythrane [erythrolide V (9)], and aquariane [aquariolides B (10) and C (11)] skeletal classes have been isolated from the encrusting gorgonian Erythropodium caribaeorum. The structures of the new compounds were elucidated by spectroscopic analysis and chemical interconversions. A biogenetic proposal that links carbon skeletons found in E. caribaeorum diterpenoids is presented. (C) Wiley-VCH Verlag GmbH Co.
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页码：3515 / 3523
页数：9
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