Singlet oxygen-mediated transformation of furans into aromatic nitrogen-containing polycycles in water

被引：7

作者：

Kalaitzakis, Dimitris ^{[1
]}

Montagnon, Tamsyn ^{[1
]}

Ioannou, Georgios I. ^{[1
]}

Antonatou, Eirini ^{[1
]}

Vassilikogiannakis, Georgios ^{[1
]}

机构：

[1] Univ Crete, Dept Chem, Iraklion 71003, Crete, Greece

来源：

ARKIVOC | 2015年

基金：

欧洲研究理事会;

关键词：

Singlet oxygen; furans; water; sustainable chemistry; green chemistry; indole; tryptamine; Pictet-Spengler; ONE-POT SYNTHESIS; ECONOMY; PHOTOOXIDATION; SYNTHESIZE; PRODUCTS;

D O I：

10.3998/ark.5550190.p008.973

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Using a sustainable, green and one-pot protocol, simple furans are transformed into complex aromatic nitrogen-bearing polycycles that are synthetically important. The reaction, which is performed in water, begins with the highly selective and mild photooxidation of the furan substrate with singlet oxygen.

引用

页码：154 / 166

页数：13

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