Synthesis and characterization of biodegradable copolymers based on 6-aminocaproic acid and α-L-alanine

被引:6
|
作者
Zhang, Weipeng [1 ]
机构
[1] Xian Jiaotong Univ, Inst Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
关键词
D O I
10.1007/s00289-007-0869-3
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Random copolymers based on 6-aminocaproic acid and alpha-L-alanine were prepared by melt phase polycondensation method and characterized by FTIR, H-1 NMR, DSC and WAXD. The density, water absorptivity and enzymatic degradation of copolymers were measured. The results show that with increasing of alanine content in comonomers, the density, water absorptivity and rate of enzymatic degradation of copolymers increase, but the intrinsic viscosity and the degree of crystallization decrease. When the molar percentage of alanine increases to 40% in comonomers, copolymer is amorphous.
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页码:323 / 330
页数:8
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