Transition state in a noisy environment

被引:78
|
作者
Bartsch, T [1 ]
Hernandez, R [1 ]
Uzer, T [1 ]
机构
[1] Georgia Inst Technol, Ctr Nonlinear Sci, Atlanta, GA 30332 USA
关键词
D O I
10.1103/PhysRevLett.95.058301
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Transition state theory overestimates reaction rates in solution because conventional dividing surfaces between reagents and products are crossed many times by the same reactive trajectory. We describe a recipe for constructing a time-dependent dividing surface free of such recrossings in the presence of noise. The no-recrossing limit of transition state theory thus becomes generally available for the description of reactions in a fluctuating environment.
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收藏
页数:4
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