Swelling characterization of the semiinterpenetrating polymer network hydrogels composed of chitosan and poly(diallyldimethylammonium chloride)

被引：49
|
作者：
Kim, SJ [1 ]
Yoon, SG [1 ]
Kim, IY [1 ]
Kim, SI [1 ]
机构：
[1] Hanyang Univ, Dept Biomed Engn, Seoul 113605, South Korea
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2004年 / 91卷 / 05期
关键词：
interpenetrating polymer network (IPN); hydrogels; swelling;
D O I：
10.1002/app.13516
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Temperature- and pH-responsive semiinterpenetrating polymer network (SIPN) hydrogels, constructed with chitosan (CS) and poly(diallyldimethylammonium chloride) (PDADMAC), were studied. The characterizations of the IPN hydrogels were investigated by fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and swelling tests, under various conditions. CS/PDADMAC SIPN hydrogels exhibited a relatively high swelling ratio, in the range of 248-462%, at 25degreesC. The swelling ratio of CS/PDADMAC IPN hydrogels are pH, temperature, and ionic concentration dependent. DSC was used for the quantitative determination of the amounts of freezing and nonfreezing water. The amount of free water increased with increasing PDADMAC content in the IPN hydrogels. (C) 2004 Wiley Periodicals, Inc.
引用
收藏
页码：2876 / 2880
页数：5
相关论文
共 50 条
  • [41] Preparation of interpenetrating polymer network composed of poly(ethylene glycol) and poly(acrylamide) hydrogels as a support of enzyme immobilization
    Lee, Yeol
    Kim, Dae Nyun
    Choi, Dongkil
    Lee, Woojin
    Park, Jinwon
    Koh, Won-Gun
    [J]. POLYMERS FOR ADVANCED TECHNOLOGIES, 2008, 19 (07) : 852 - 858
  • [42] Interpenetrating polymer network hydrogels composed of chitosan and photocrosslinkable gelatin with enhanced mechanical properties for tissue engineering
    Suo, Hairui
    Zhang, Deming
    Yin, Jun
    Qian, Jin
    Wu, Zi Liang
    Fu, Jianzhong
    [J]. MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2018, 92 : 612 - 620
  • [43] SYNTHETIC HYDROGELS .8. PHYSICOCHEMICAL PROPERTIES OF N,N-DIMETHYLACRYLAMIDE SEMIINTERPENETRATING POLYMER NETWORK HYDROGELS
    CORKHILL, PH
    TIGHE, BJ
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (05) : 491 - 496
  • [44] Synthesis and characterization of cross-linked quaternized chitosan/poly(diallyldimethylammonium chloride) blend anion-exchange membranes
    Yuan Yuan
    Chunhui Shen
    Jiqin Chen
    Xuechao Ren
    [J]. Ionics, 2018, 24 : 1173 - 1180
  • [45] Synthesis and characterization of cross-linked quaternized chitosan/poly(diallyldimethylammonium chloride) blend anion-exchange membranes
    Yuan, Yuan
    Shen, Chunhui
    Chen, Jiqin
    Ren, Xuechao
    [J]. IONICS, 2018, 24 (04) : 1173 - 1180
  • [46] Temperature and pH sensitive hydrogels composed of chitosan and poly(ethylene glycol)
    Khurma, Jagjit R.
    Nand, Ashveen V.
    [J]. POLYMER BULLETIN, 2008, 59 (06) : 805 - 812
  • [47] Temperature and pH sensitive hydrogels composed of chitosan and poly(ethylene glycol)
    Jagjit R. Khurma
    Ashveen V. Nand
    [J]. Polymer Bulletin, 2008, 59 : 805 - 812
  • [48] Inverted Polymer Solar Cells with a Poly(diallyldimethylammonium chloride) as an Electron Collecting Layer
    Kim, Wook Hyun
    Lee, Sang-Ju
    Jeon, Boram
    Sung, Shi-Joon
    Woo, Sungho
    [J]. SCIENCE OF ADVANCED MATERIALS, 2014, 6 (11) : 2334 - 2337
  • [49] Swelling and electroresponsive characteristics of interpenetrating polymer network hydrogels
    Yoon, SG
    Kim, IY
    Kim, SI
    Kim, SJ
    [J]. POLYMER INTERNATIONAL, 2005, 54 (08) : 1169 - 1174
  • [50] Synthesis and characterization of poly(diallyldimethylammonium chloride) in a broad range of molecular weight
    Dautzenberg, H
    Gornitz, E
    Jaeger, W
    [J]. MACROMOLECULAR CHEMISTRY AND PHYSICS, 1998, 199 (08) : 1561 - 1571
12345