Progress in asymmetric biomimetic transamination of carbonyl compounds

被引：64

作者：

Xie, Ying ^{[1
]}

Pan, Hongjie ^{[1
]}

Liu, Mao ^{[1
]}

Xiao, Xiao ^{[1
]}

Shi, Yian ^{[1
,2
,3
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China

[2] Nanjing Univ, Sch Chem & Chem Engn, Ctr Multimol Organ Chem, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

[3] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2015年 / 44卷 / 07期

关键词：

ALPHA-KETO ESTERS; BETA-AMINO ACIDS; SUPRAMOLECULAR BILAYER-MEMBRANE; PYRIDOXAMINE ENZYME ANALOGS; NONENZYMATIC TRANSAMINATION; ARTIFICIAL AMINOTRANSFERASE; ENANTIOSELECTIVE CATALYSIS; STEREOSELECTIVE TRANSAMINATION; METAL-COMPLEXES; SHIFT REACTION;

D O I：

10.1039/c4cs00507d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transamination of alpha-keto acids with transaminases and pyridoxamine phosphate is an important process to form optically active alpha-amino acids in biological systems. Various biomimetic transamination systems have been developed for carbonyl compounds including a-keto acid derivatives, fluoroalkyl ketones, and unactivated ketones with chiral vitamin B-6 analogues, artificial transaminase mimics, chiral nitrogen sources, and chiral catalysts. This review provides a brief summary of this area.

引用

页码：1740 / 1748

页数：9

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