Progress in asymmetric biomimetic transamination of carbonyl compounds

被引：64
|
作者：
Xie, Ying [1 ]
Pan, Hongjie [1 ]
Liu, Mao [1 ]
Xiao, Xiao [1 ]
Shi, Yian [1 ,2 ,3 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Beijing 100190, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, Ctr Multimol Organ Chem, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
[3] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
来源：
CHEMICAL SOCIETY REVIEWS | 2015年 / 44卷 / 07期
关键词：
ALPHA-KETO ESTERS; BETA-AMINO ACIDS; SUPRAMOLECULAR BILAYER-MEMBRANE; PYRIDOXAMINE ENZYME ANALOGS; NONENZYMATIC TRANSAMINATION; ARTIFICIAL AMINOTRANSFERASE; ENANTIOSELECTIVE CATALYSIS; STEREOSELECTIVE TRANSAMINATION; METAL-COMPLEXES; SHIFT REACTION;
D O I：
10.1039/c4cs00507d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Transamination of alpha-keto acids with transaminases and pyridoxamine phosphate is an important process to form optically active alpha-amino acids in biological systems. Various biomimetic transamination systems have been developed for carbonyl compounds including a-keto acid derivatives, fluoroalkyl ketones, and unactivated ketones with chiral vitamin B-6 analogues, artificial transaminase mimics, chiral nitrogen sources, and chiral catalysts. This review provides a brief summary of this area.
引用
收藏
页码：1740 / 1748
页数：9
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