Synthesis of sterically hindered 1,3-diketones

被引：16
|
作者：
Nandurkar, Nitin S. [1 ]
Bhanushali, Mayur J. [1 ]
Patil, Dinkar S. [2 ]
Bhanage, Bhalchandra M. [1 ]
机构：
[1] Inst Chem Technol, Dept Chem, Bombay 40019, Maharashtra, India
[2] Bhabha Atom Res Ctr, Div Laser & Plasma Technol, Bombay 400085, Maharashtra, India
来源：
SYNTHETIC COMMUNICATIONS | 2007年 / 37卷 / 22-24期
关键词：
claisen condensation; 1,3-diketone; ester; potassium tert-butoxide;
D O I：
10.1080/00397910701572803
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient and practical method for the synthesis of sterically hindered aliphatic/aromatic 1,3-diketones via coupling of ketones with esters using potassium tert-butoxide is described. The protocol requires milder operating conditions, and the products are obained in good to excellent yields.
引用
收藏
页码：4111 / 4115
页数：5
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