Solvent-free synthesis of new inorganic-organic hybrid solids with finely tuned manganese oxalate structures

被引:11
|
作者
Luan, Lindong [1 ]
Li, Jing [2 ]
Yin, Changzhen [2 ]
Lin, Zhien [2 ]
Huang, Hui [1 ]
机构
[1] Beijing Inst Technol, Sch Chem, Beijing 100081, Peoples R China
[2] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China
关键词
OPEN-FRAMEWORK STRUCTURES; HOST-GUEST SYMMETRY; ZINC PHOSPHATE; NICKEL(II) PHOSPHATE; MAGNETIC-PROPERTIES; ZEOLITES;
D O I
10.1039/c5dt00431d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Three manganese phosphate-oxalates have been synthesized under solvent-free conditions. These inorganic-organic hybrid solids are based on a pcu-type topology with nanobelt-like, sql-, and cds-type manganese oxalate skeletons, respectively. The amine molecules play a novel structure-directing role for the formation of different metal-organic skeletons within a specific framework topology.
引用
收藏
页码:5974 / 5977
页数:4
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