Pressure-induced change in orientational order of solutes in liquid crystals

被引:2
|
作者
Burnell, EE
de Lange, CA
Gaemers, S
机构
[1] Univ British Columbia, Dept Chem, Vancouver, BC V6T 1Z1, Canada
[2] Univ Amsterdam, Phys Chem Lab, NL-1018 WS Amsterdam, Netherlands
[3] Univ Amsterdam, Inorgan Chem Lab, NL-1018 WV Amsterdam, Netherlands
基金
加拿大自然科学与工程研究理事会;
关键词
D O I
10.1016/S0009-2614(01)00204-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The H-1 and H-1 NMR spectroscopy of the nematic liquid crystal ZLI 1132 containing small amounts of the solutes 1,3,5- trichlorobenzene. p-dichlorobenzene and acetone was investigated as a function of the pressure of a mixture of molecular hydrogen and deuterium gases above the sample. A general increase of solute orientational order with pressure was observed. Differences in behavior of the orientational order of the hydrogens compared to the other solutes are discussed. (C) 2001 Elsevier Science B.V. All rights reserved.
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页码:248 / 254
页数:7
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