Synthesis of (C8H11N)2•Zn(OAc)2, (C8H11N)2•Cu(OAc)2, and (C8H11N)2•CuCl2 complexes and application to the Henry reaction

被引：1

作者：

Mei, L. ^{[1
]}

Jie, C. ^{[1
]}

Yang, H. B. ^{[1
]}

Ming, Z. S.

Hao, Y.

Ming, T. H. ^{[1
]}

机构：

[1] Hefei Univ Technol, Dept Chem Engn, Hefei 230009, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 52卷 / 04期

关键词：

(C8H11N)(2)center dot Zn(OAc)(2); (C8H11N)(2)center dot Cu(OAc)(2); and (C8H11N)(2)center dot CuCl2 complexes; crystal structures; catalysts; Henry reaction; COPPER(II); ZINC(II); NICKEL(II); LIGANDS; CATALYST; BINDING;

D O I：

10.1134/S0022476611040159

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(C8H11N)(2)center dot Zn(OAc)(2) (1a), (C8H11N)(2)center dot Cu(OAc)(2) (1b), and (C8H11N)(2)center dot CuCl2 complexes are synthesized by a simple one-pot method. The crystal structures of 1a, 1b, and 1c are determined by X-ray crystallography. The complexes are also characterized by NMR, IR, MS, and elemental analysis and used as the catalysts applied to the Henry reaction; moderate to high yields are obtained at room temperature.

引用

页码：748 / 754

页数：7

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